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CLEANUP AND ABATEMENT ORDER NO. R5-2006-0720 <br /> NESTLE USA, INC. <br /> RIPON, SAN JOAQUIN COUNTY <br /> these new wells. Additional monitoring wells need to be installed in the Lower Aquifer Zone to <br /> provide early detection of plume migration towards these supply wells. <br /> 12. Based on historical monitoring in the Upper and Intermediate aquifer zones beneath the Facility, <br /> TCE,cis-1,2-dichlorethene,vinyl chloride, and chloroform are the primary VOCs detected in <br /> groundwater. Other constituents of concern detected in groundwater beneath the Facility include <br /> tetrachloroethene, 1,1,1-trichloroethane,trans-1,2-dichloroethene, 1,1-dichloroethene, 1,2- <br /> dichloroethane, 1,1-dichloroethane, methylene chloride,carbon tetrachloride, and bromoform. <br /> Carbon tetrachloride and tetrachloroethene appear to originate from sources not associated with the <br /> Discharger. On 4 April 2006,the Discharger submitted the Draft 2005 Annual Groundwater <br /> Monitoring Report. Concentrations of VOCs have generally declined one to two orders of <br /> magnitude in most monitoring wells since discovery of the release in 1985. However,the plume has <br /> spread laterally and vertically since 1985 and recent vertical profiling of the Upper Aquifer Zone <br /> discovered residual concentrations of TCE as high as 7,800 µg/L in the Industrial Avenue source <br /> area(Geomatrix 2006). Maximum concentrations of VOCs in the Discharger's groundwater <br /> monitoring wells (Figure 3)in 2005 are presented in the table below: <br /> Constituent Concentration <br /> Trichloroethene 590 <br /> Cis-1,2-dichloroethene 250 <br /> Vinyl Chloride 220 <br /> Chloroform 12 <br /> Tetrachloroethene 2.2 <br /> 1,1,1-Trichloroethane 0.16 <br /> Trans-1,2-dichloroethene 4.1 <br /> 1,1-Dichloroethene 3.4 <br /> 1,2-Dichloroethane <0.5 <br /> 1,1-Dichloroethane 6.5 <br /> Methylene chloride 0.52 <br /> Bromoform 2.3 <br /> 13. The Discharger has monitored local supply wells since 1986. VOCs,principally TCE and cis-1,2- <br /> DCE, have been detected in existing municipal supply wells MW-7 and MW-9. Concentrations of <br /> these VOCs have exceeded California Primary Maximum Contaminant Levels (MCLs) in MW-9. In <br /> 1998,the City of Ripon installed a granular activated carbon(GAC) unit on MW-9 to treat VOCs <br /> originating from the Discharger's former facility. Concentrations of TCE in well MW-7 have <br /> exceeded the California Public Health Goal (PHG),but have been below the MCL. TCE and/or cis- <br /> 1,2-DCE have also been detected in former municipal wells MW-1 and MW-6 and former Simpson <br /> Paper Company production wells PW-04 and PW-05,but use of these wells was discontinued for <br /> reasons unrelated to the TCE plume. <br /> 14. In 1990,the Discharger submitted a Draft Risk Assessment that evaluated the degree of risk to <br /> human health posed by the groundwater TCE plume. At the time that report was submitted,the <br /> Discharger believed that the TCE plume had not migrated far from the Facility and the report <br /> concluded that there was no complete pathway to potential receptors including the local municipal <br /> supply wells. <br /> 4 <br />