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ATC Associates Inc. <br /> 1117 Lone Palm Avenue,Suite B <br /> Modesto,California 95351 <br /> 209-579-2221 <br /> Fax:209-579-2225 <br /> encapsulated 03, created by forcing an air/03 mixture through fine-pore ozone diffusers, otherwise <br /> known as Spargepoints®, into soil or groundwater. Figure 2 shows the remediation system compound <br /> location as well as the injection and groundwater monitoring well network for the site. Five injection <br /> wells (IWI through IW5) at the site consist of two Spargepoints® positioned within an eight-inch <br /> diameter boring. Injection wells IW6 and IW7 are both of single completion construction. Table 1 <br /> includes a summary of the injection well completion details. Each Spargepoine consists of a 30" long, <br /> 1-inch diameter fine-pore ozone diffuser coupled to its own blank, 1/4-inch inside diameter casing,which <br /> extends to the surface. <br /> The injection of 03 into individual Spargepoints® occurs at separate, pre-programmed injection <br /> intervals. During the reporting period associated with the first quarter of 2012 (from December 20, <br /> 2011 to April 5, 2012), 03 was injected sequentially in IWI(s), IWI(d), IW2(s), IW2(d), IW3(s), <br /> IW3(d), IW6, and IW7. The ozone injection times per cycle consisted of 5 minutes each for IW 1(d)and <br /> IW2(d); 10 minutes each for IWI(s), IW2(s), IW3(s), and IW3(d); and 15 minutes each for IW6 and <br /> IW7. Consequently, ozone was injected into the subsurface for 80 minutes followed by a 10 minute <br /> shut-off period before the cycle repeated. <br /> The ozone injection system shut down sometime between December 20, 2011,and January 9, 2012, due <br /> to an air compressor failure. Following repairs to the air compressor on January 9, 2012,the system was <br /> restarted and operated continuously from January 9 through April 5, 2012 for approximately 1,828 <br /> hours. Due to a theft at the project site, a complete copy of the operational data for this time period is <br /> not available. Available field data are included in Attachment 1. <br /> Vadose Zone Remediation <br /> Startup of the SVE system and initial vapor sampling was conducted on October 17, 2011. During the <br /> startup of the vapor extraction system, flow rate readings were at 152 cubic feet per minute (cfm) and <br /> temperature was registering between 1,092 and 1,631°F. After initial monitoring with a photoionization <br /> detector (PID) of VWl through VW3, the valve for VWI was left fully open and the valves for VW2 <br /> and VW3 remained one half open. <br /> Vapor samples collected on October 17, 2011, were submitted to State-certified laboratory Test <br /> America, Inc. with appropriate chain-of-custody documentation. The lab is certified under an <br /> Environmental Laboratories Accreditation Program. Chemical analyses of total petroleum hydrocarbons <br /> as gasoline (TPHg) and benzene, toluene, ethylbenzene and xylenes (BTEX) was performed utilizing <br /> Method TO-15. <br /> TPHg and BTEX were detected the influent sample and BTEX were detected in the effluent sample. <br /> Analytical results for the influent sample detected TPHg vapors at a concentration of 910 parts per <br /> million by volume (ppmv). TPHg results for the effluent were reported below a detection limit of 7.2 <br /> ppmv. Laboratory results of the effluent and influent vapor samples indicate a destruction efficiency of <br /> greater than 95%.Utilizing concentration and flowrate,the emission rate was calculated at an average of <br /> 0.35 pounds per day. Analytical results and the destruction efficiencies for each detected analyte are <br /> Jamar Status Rpt 1 Q 2012 4 <br />