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1 <br /> ' ■ The cumulative mass of contaminants removed from the dissolved phase for the site over <br /> time as monitored by changes in concentration and/or areal extent in map view. <br /> ' ■ The overall effectiveness of the C-SpargeTM remediation system as monitored by one <br /> additional indicator to be added during 4th Quarter 2004: <br /> 1. Oxidation-reduction potential (ORP) field determinations on groundwater grab <br /> ' samples. ORP conditions over 300 my usually indicate the presence of gaseous <br /> 03. <br /> After significant reduction of MTBE, the quantification of the: <br /> - Overall contaminant mass destruction rates (Le., removal efficiency) for the site <br /> over time, and to the extent practical; <br /> - Contaminant mass destruction rates for the site with distance and direction from <br /> ' the injection wells over time. <br /> [Note: Reduction of benzene is expected prior to MTBE.] <br /> ' 4.4.2 Results of Remediation System Monitoring <br /> A summary of depth to water, groundwater elevation and groundwater flow has been described <br /> ' previously in this report (Table 1). Groundwater chemistry has been reported in Table 2. <br /> The depth to groundwater during the July 16, 2004 groundwater monitoring event for on-site <br /> wells (only) ranged from 65.40 to 66.16 feet bgs where measured. The depth to groundwater <br /> during the third quarter for the August 13, 2004 groundwater-monitoring event for on-site wells <br /> (only) ranged from 66.37 to 66.73 feet bgs where measured. The depth to groundwater during the <br /> ' September 13, 2004 groundwater-monitoring event for on-site wells (only) ranged from 66.83 to <br /> 67.18 feet bgs. The upper ozone diffusers were a minimum of 5.34, 4.77 and 4.32 feet below the ,. <br /> top of water, respectively, during the July, August and September monitoring events. <br /> ' 4.5 Analysis of System Effectiveness <br /> ' Figures 14 through 20 are cross plots of benzene and MTBE over time. Figures 21, 22 and 23 <br /> show the areal distribution of benzene, MTBE and TPHg, respectively, based on isoconcentration <br /> maps over time. <br /> 4.5.1 Benzene <br /> Prior to this monitoring period, and prior to remediation system start-up on June 17, 2004 at the <br /> ' Jamar property, benzene concentrations appeared to decline in MW2, MW3, MW4, MWS and <br /> MW8. <br /> ' Declining trends in benzene concentration were not evident, however, in MW1 and EW1 prior to <br /> this monitoring period. During the third quarter monitoring period concentrations of benzene <br /> from MW1 and EW1 placed respectively at approximately 7.5 and 9.0 feet from the closest <br /> Spargepoint® (IW2 and IW1) declined. <br /> The successive decline of benzene in MW1 from the 37,000 ug/L on June 3, 2004 in each of the <br /> ' monitoring events following (i.e., July 16, 2004, August 13, 2004 and September 13, 2004) was <br /> 5:1268231QM reports12004 3QR.doc 8 ATC Associates Inc. <br />