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GCIMS Methods GC Methods GCIMS Methods GC Methods Method/ Modified Modified Modified Modified Modified COMMENTS Method/ Modified Modified Modified Modified Modified COMMENTS Parameter USEPA 8260 USEPA TO- USEPA TO-17 USEPA 8015 USEPA 8021 Parameter USEPA 8260 USEPA TO. USEPA TO-17 16 16 USEPA 8015 USEPA 8021 One per 20 One per 20 One per 20 One per 20 See 1.Analyticzl One per 20 samples samples or samples a samples or samples or Appendix F protocol as Duplicates or batch,whichever batch, batch, batch, batch, of this per USEPA Is more often. whichever Is whichever Is whichever Is whichever is 9ufor TO-1 more often. more often. more often. more often. disccance ussion. freshly Condition %RPD-25%. fleshy packed One per 20 One per 20 One per 20 One per 20 See (new)sorbent One per 20 samples samplesa samples or samples a or Appendix F P a samples P Replicates Is batch.whichever batch, batch, batch, batch, guidance for analyze routine of this 3.Collect and Use only for Use only for Is more often. whichever is whichever is whichever is whichever Is discussion. 'Distributed routine more often. more often. more often. more often. %RPD-25%. 1.Tuning:50 Volume Pairs" monitoring at well. monitoring at . See ng BFB fa characterized well- Appendix F , Initially and uncharacter- sites.Other characterized Laboratory Control every 24 Ized sites. Idles. Optional Na Required Not Required. Optional Optional of this than Ti Identification Samples(LCS) hours.Meet 4.Determine/ guidance for identification discussion. acceptance validale'Safe of new of new criteria as per Sampling compounds See Tuning: 50 ng compounds be See See Table 3 of Volume' must m Me hod Detection See Appendix F of See Appthis Mx See Appthis tz Appendix F Appendix F Appendix F Brom(BFB)initially USEPA TO- (SSV)8 must be -confirmed F of this F of this of this (BFB)Initlely and conformed LimlVReponing Limit this guidance. of this of This 15. needed as per either by guidance. guidance. guidance, guidance. 9uklance for Other Requirements every 12 hogs. Sections 10.8 either by. second discussion. Meet acceptance second See criteria as per Table 2.Must meet alt 13.7.2 d column or column a equipment USEPA TO- different One per One per One per Appendix F 4 of USEPA 8260. detector, Reporting Limit One per batch of One per batch specifications 17;analyze as detector,and Verification samples.10 batch of of samples.to batch of i batch of t t of this In Section 7.2 per USEPA detector,of then 10%of samples."' samples. samples. guidance fa then 10%of of USEPA TO-15 and those discussion. those TO-15 f,US n 11.2 samples Method blank Method blank repot results`" of USEPA samples must be using using most be as rtxldlfled TO-17. withaconfirmed Method blank using humidified humidified sA with a ed humidified lab grade As As TO-t. «. 5.Anaydcel with a W per Section lab gads lab grade � ° precision lest with a GCIMS Method Blanks ultra pure ad/as Section 10.7 10.7.1 of ultra pure air uWe pwe atr GCIMS as per Section method. sample and per of USEPA USEPA TO- as sample as sample method. Section 8.4.1 of TO-15. 17. and per and per a ., ,. 11.3.2.2 of USEPA 8260. Section 9.5 Section 8.4 & U7EPA TO- of USEPA of USEPA 6 8015C. 8021. Performance Monitor other One sample One sorbent One sample One sample _ Sectile 1 per One Semple components container per tube blank per contains per container per Section 14 of contains r 20 (i.e.,fittings/-� 20 samples a 20 samples a 20 samples 20 samples USEPA TO- Container Blank samples or valves)of batch whiFhever Is` Per batch, per batch, or per batch, or per batch, sampling 17. whichever is whichever is whichever is whichever is more oher5'w often. more often. more often. more often. system it moreY needed. 'Adapted from"Guide to Environmental Analytical Methods"5N Edition,Edited by Roy-Keith Smith,Ph.D., Analyze Analyze Genlum Publishing Corp.,2003. Analyze Analyze ASAP. ASAP. ASAP.Up to ASAP.Up to Samples Samples 771 Anayze ASAP. 14 days for 30 days collected in collected in Initial,one-time,demonstration of ability to generate acceptable accuracy and precision. Procedure Samples collected in samples in refrigerated. passivated passlvated may need to be repeated if changes In Instrument,methodology or personnel occur. USEPA Method passevated canisters Bolding Time canisters. Exceptions as canisters can be held up 80008(Determinative Chromatographic Separations),Revision 2,December 1996(SW-846 Manual). can be held up to 14 canistss. noted In be held up to be held up to days.Tedlar®bag Tedlar®bag Section 10.10 14 days. 14 days. to Mid-level NIST(National Institute of Standard and Technology)traceable(where available or use Is discouraged. use Is of USEPA TO- Tedlare bag Tedlars bag discouraged. 17. use Is use is equivalent)vapor-phase standard. discouraged. discoura ed. t'1 No internal standards and surrogates were suggested by the method. The compounds are to be selected by the analyst(lab)and they must be similar in analytical behavior to the compounds of interest. The analyst needs to demonstrate the internal standards are not affected by method or matrix interferences. IU There Is no limit on the number of samples per batch for Reporting Limit Verification. Once per day Is sufficient 3/3/2010 -39- 3/3/2010 -40-