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Mr. Jeff Baker . - 2 - 30 May 2008 <br /> Stockton Terminals Technical Committee <br /> wells contained SPH. The highest COC concentrations typically underlie the BP and Time Oil <br /> facilities. During the first quarter 2008, the highest COC concentrations were generally in A zone <br /> wells on the Time Oil property. The highest concentrations of TPHg and TPHd were in TS-4 at <br /> 100,000 micrograms per liter (Ng/L) and 360,000 pg/L, respectively. The highest concentration of <br /> TBA, however, was in the D zone at 1,700 pg/L in well TS/MW-2D. <br /> The OS system installed in 2004 is divided into two portions. The west system is downgradient of <br /> Tesoro and the east system is downgradient of BP. Between December 2007 and March 2008, <br /> the STTC estimates that the east system and west system had run times of 81 and 64 percent, <br /> respectively. The STTC estimates that collectively 241 pounds of hydrocarbons were destroyed <br /> during this period. <br /> The STTC conducts an OS system monitoring program in six A and B zone remedial observation <br /> wells (PS/MW-18, PS/WC-1 S, AR/MW-21 A. AR/MW-18B, AR/MW-21 B, PS/WC-1 M). A <br /> contingency plan is triggered if petroleum hydrocarbon concentrations (excluding TPH) exceed <br /> historical concentrations by one order of magnitude for three consecutive quarters in any of these <br /> six wells. This condition was not observed in any remedial observation wells during the first <br /> quarter of 2008. <br /> The Work Plan proposes to install four monitoring wells (PS/MW-20A through PS/MW-20D) to <br /> address a gap in the monitoring well network between wells OW-8D and OW-51D. PS/MW-20A <br /> will only be installed if attempts to locate the existing well PS/MW-20 fail. The STTC anticipates <br /> that a report describing the installation will be submitted to Regional Water Board staff within six <br /> to eight weeks following receipt of the final laboratory analytical data. <br /> Our comments are presented below. <br /> 1. The STTC had originally recommended installing a single D-zone monitoring well. However, <br /> Regional Water Board staff concur with the STTC's recommendation for installing B, C and D <br /> zone wells, and if necessary, an A-zone monitoring well if PS/MW-20 cannot be located. By <br /> 19 September 2008, please submit a report on the well installations. <br /> 2. A copy of the ozone injection monitoring program contingency plan is included as Attachment <br /> 3 in the Work Plan. The ozone injection monitoring program, which was formulated by the <br /> STTC in June 2003, does not specify which petroleum hydrocarbons increases in the <br /> remedial observation wells will be monitored to trigger implementation of the contingency <br /> plan. The data trends for remedial observation well AR/MW-18B are tabulated in Appendix I <br /> of the first QMR. Historical concentration data for benzene, MTBE, and TPHg in AR/MW-18B <br /> show increasing concentration trends over the two quarters preceding the first quarter of <br /> 2008. Because the concentration increases for these three constituents did not exceed <br /> historical averages or were not part of the list of"trigger" hydrocarbons, implementation of the <br /> contingency plan was not warranted. <br /> The data trends show that TBA sustained concentration increases over three consecutive <br /> quarters, in excess of the only existing historical data point of<5.0 pg/L, from May 2006 to <br /> November 2006, and from August 2007 to February 2008. The February 2008 detection of <br /> 9.4 pg/L is the highest TBA concentration ever observed in AR/MW-18B However, TBA is not <br /> among the list of trigger hydrocarbons in the ozone injection monitoring program. The recent <br />