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Mr. Jeff Baker - 2 - 31 August 2010 <br /> Stockton Terminals Technical Committee <br /> During the second quarter 2010, the highest dissolved COC concentrations generally <br /> occurred in A zone wells in the BP aboveground tank (AGT) area and in the southeast <br /> corner of the Tesoro property. In the deeper zones, maximum concentrations were <br /> encountered on the Tesoro property. The highest concentrations of TPHg and TPHd <br /> were in AR/MW-24A and TS/M-2, at 69,000 micrograms per liter (Ng/L) and <br /> 160,000 pg/L, respectively. The highest concentration of benzene was detected in <br /> AR/MW-813 at 15,000 pg/L. The highest concentrations of MTBE and TBA were <br /> detected in TO/T-2 and AR/MW-50 at 15,000 pg/L and 2,400 pg/L, respectively. <br /> Groundwater at the BP facility is polluted with MBAS. BP believes the pollution <br /> originates from a November 2008 fire suppression foam release. The water quality <br /> objective (WQO) for MBAS is 500 pg/L. To address the concentrations, BP over-purges <br /> up to 10 well casing volumes from wells containing MBAS before sampling. BP <br /> describes over-purging as the process of removing 10 well casing volumes from a <br /> monitoring well prior to sampling. Table 6 shows that the maximum MBAS detection <br /> was 16,000 pg/L in AR/MW-21 C. During the second quarter 2010, BP over-purged <br /> 20 wells and, due to groundwater volume limitations, unsuccessfully attempted to over- <br /> purge an additional four wells. The Second QMR states that over-purging removed <br /> about 4,370 gallons of groundwater during the second quarter. <br /> As we requested in our 11 March 2010 letter, during the second quarter BP sampled for <br /> MBAS in all BP wells and in select downgradient Port of Stockton wells, including <br /> PS/MW-20C, OW-3CR, OW-4C, and OW-9C. MBAS was detected in all of the wells. <br /> Concentrations in two wells exceeded the WQO of 500 pg/L. <br /> In the fall of 2004, the STTC began operation of two ozone sparge (OS) systems to <br /> clean up groundwater pollution migrating downgradient from the Site. The system is <br /> comprised of 57 A zone and 16 B zone wells connected to two 2 pounds-per-day <br /> (Ibs/day) ozone generators. The OS system is divided into two portions. The west <br /> system is downgradient of Tesoro, and the east system is downgradient of BP. During <br /> the second quarter, the STTC estimates that the east system and west system had <br /> ozone sparge run times of about 95 and 91 percent, respectively. The STTC estimates <br /> that historically, about 8,800 pounds of ozone have been injected and 2,950 pounds of <br /> hydrocarbons have been destroyed. <br /> The STTC monitors the ozone injection system using an array of six remedial <br /> observation (RO) wells, two midpoint wells, and four trigger wells. A contingency plan is <br /> triggered if the concentration of BTEX, MTBE or TBA in any RO well exceeds <br /> compliance limits. Table 7 shows that the TBA concentration in RO well AR/MW-18B <br /> decreased from 44 pg/L during the first quarter to 18 pg/L during the second quarter. <br /> These concentrations exceed the compliance limit of 6.6 pg/L. Pursuant to the terms. <br /> described on Page 3 of the Revised Contingency Plan (Appendix K of the First QMR), <br /> three consecutive exceedences of an order of magnitude greater than the compliance <br /> limit will trigger installation of a second ozone sparge array east of the RO wells. None <br /> of the concentrations measured so far has been an order of magnitude above the <br /> compliance limit. <br />