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Mr. Jeff Baker <br /> Stockton Terminals Technical Committee 3 31 August 2010 <br /> The Revised Contingency Plan also sets compliance limits consisting of the WQOs for <br /> BTEX and MTBE in four trigger wells located downgradient of the RO wells. Three <br /> consecutive exceedences of the WQO would trigger installation of another ozone <br /> sparge array east of the trigger wells that include OW-2A, OW-4A, OW-26, and <br /> OW-413. During the second quarter, BTEX and MTBE concentrations were not detected <br /> above their WQOs. <br /> Based on the groundwater monitoring data in the Second QMR, STTC concludes that <br /> (1) the overall hydrocarbon concentration trends in groundwater beneath and downgradient <br /> of the Site appear relatively stable to decreasing, (2) results from the ozone injection <br /> monitoring program indicate the East and West remedial systems are effectively mitigating <br /> off-site migration of petroleum hydrocarbons and (3) sampling in TS/MW-3D should be <br /> discontinued. <br /> STTC member company Tesoro is presently conducting two pilot studies of remedial <br /> technologies. <br /> A 1-year, D-zone oxygen injection pilot study proposed in the 27 January 2009 Pilot <br /> Study Work Plan and Revised Contingency Plan is being conducted at TS/MW-1 D. <br /> Instead of injecting oxygen, Tesoro will be using a passive source of oxygen, such as <br /> the Waterloo EmitterT^^ (WE), a down-hole apparatus which is connected to pressurized <br /> Pure oxygen. <br /> Tesoro commenced the study by conducting the TS/MW-2D helium-tracer study <br /> between June and October 2009. Based on these observations, injection wells <br /> TS/MW-3DR and TS/MW-4D were installed and developed during March 2010. <br /> TS/MW-3D was redeveloped on 3 June to remove sediment from the casing. The <br /> helium tracer test to confirm hydraulic communication between TS/MW-3DR and <br /> TS/MW-2D was conducted on 30 June 2010. Documentation of the tracer test and the <br /> well installations will be presented under separate cover. <br /> Based on the work plan, baseline groundwater monitoring was conducted for dissolved <br /> oxygen/oxidation reduction potential (DO/ORP), biodegradation parameters, and Bio <br /> Traps® in the month prior to beginning the study. Groundwater monitoring for the <br /> oxygen injection study will be conducted monthly during the first three months of the <br /> 1-year study and quarterly thereafter. Tesoro anticipates that oxygen will be delivered <br /> via the WE at a rate of about 3.64 liters per day. <br /> Tesoro is also conducting a hydrogen peroxide injection (HPI) pilot study at the <br /> southwest property boundary shared with Time Oil in the vicinity of TS-4R. Baseline <br /> ._,groundwater monitoring was conducted in four wells described by Tesoro as upgradient <br /> well (TO/T-3), treatment zone wells (TS-413, TS/M-2), and downgradient well (TS-5) for <br /> four quarters to determine baseline values for total chromium, hexavalent chromium, <br /> vanadium, bromide, and bromate. Injection of the hydrogen peroxide into treatment <br /> zone wells TS/RW-1 and TS-413 may mobilize these metals. Table 8 lists the laboratory <br /> analytical results of the baseline monitoring and the results of twice-monthly sampling <br /> following the first hydrogen peroxide injection that occurred on 23 March 2010. <br />