Laserfiche WebLink
Mr. Jeff Baker • -3- • 11 March 2010 <br /> Stockton Terminals Technical Committee <br /> 2009, the STTC estimates that the east system and west system had ozone sparge run <br /> times of 64 and 86 percent, respectively. Run time difficulties are attributed to system <br /> malfunctions and maintenance activities for recent system upgrades. The STTC <br /> estimates that historically' about 8,000 pounds of ozone have been injected and 2,600 <br /> pounds of hydrocarbons have been destroyed. <br /> The STTC monitors the ozone injection system using an array of six remedial <br /> observation (RO) wells, two midpoint wells, and four trigger wells. A contingency plan is <br /> triggered if the concentration of BTEX, MTBE or TBA in any RO well exceeds <br /> compliance limits. Table 7 shows that the TBA concentration in RO well AR/MW-18B <br /> increased from 31 pg/L to 49 pg/L during 2009. These concentrations exceed the <br /> compliance limit of 6.6 pg/L. Pursuant to the terms described on Page 3 of the Revised <br /> Contingency Plan (Appendix K of the Annual Report), three consecutive exceedences <br /> of an order of magnitude greater than the compliance limit will trigger installation of a <br /> second ozone sparge array east of the RO wells. None of the concentrations <br /> measured so far has been an order of magnitude above the compliance limit. <br /> The Revised Contingency Plan also sets compliance limits consisting of the WQOs for <br /> BTEX and MTBE in four trigger wells located downgradient of the RO wells. Three <br /> consecutive exceedences of the WQO would trigger installation of another ozone <br /> sparge array east of the trigger wells that include OW-2A, OW-4A, OW-26, and <br /> OW-46. During 2009, TPHd, which has displayed an increasing trend in monitoring <br /> wells OW-4B and OW-4C, was detected at 1,200 pg/L and 1,300 pg/L, respectively. <br /> However, neither OW-4C nor TPHd trigger the contingency plan. <br /> STTC member companies Tesoro and BP have conducted pilot studies of remedial <br /> technologies on their respective terminals. <br /> BP's 29 October 2009 Helium Tracer Study for Biosparging Feasibility Report <br /> summarized the results of a two-day A zone biosparge feasibility study on the BP <br /> facility to evaluate communication between potential injection and monitoring wells. <br /> Based on the results of the study, BP opted to evaluate alternate remedial <br /> technologies, including the possible use of passive diffusers. <br /> The results of a modified version of the helium-tracer, oxygen-injection pilot study were <br /> summarized in Tesoro's 16 December 2009 Helium Tracer Study Report. Based on <br /> these observations, Tesoro recommends proceeding with the 1-year, D zone, oxygen <br /> injection pilot study proposed in the 27 January 2009 Pilot Study Work Plan and <br /> Revised Contingency Plan. Tesoro proposes to install two additional wells: replacement <br /> injection well TS/MW-3DR, screened from 110 to 115 feet bgs between TS/MW-3D and <br /> TS/MW-2D, and TS/MW-4D screened from 125 to 135 feet bgs. <br /> Instead of injecting oxygen, Tesoro recommends using a passive source of oxygen, <br /> such as the Waterloo Emitter TM, a down-hole apparatus which is connected to <br /> pressurized pure oxygen. Molecular oxygen is diffused, rather than sparged, directly <br /> into surrounding groundwater, with the goal of attaining maximum dissolved oxygen <br /> (DO) solubility. We concurred with Tesoro's proposal to proceed with the pilot study. <br />