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' 5440-5606 Pacific Avenue -2- 4 October 2004 <br /> Stockton, San Joaquin County <br /> contaminant distribution in deeper aquifer zones Also,there appears to be some recent plume movement <br /> in shallow groundwater to the north and east of 5606 Pacific Avenue <br /> By 15 November 2004, submit a geochemical evaluation(GE)report signed by a geochemist, which <br /> compares the results of the soil and groundwater analyses,and thoroughly discusses the expected worst- <br /> case scenario reactions,i e, 100%conversion of constituents of concern into contaminants,reporting the <br />' chemical reactions in molar concentrations <br /> 1 If metals of concern(Cr"",etc)are not detected,or general minerals (SO4,etc)are not present at <br /> levels favorable for adverse reactions in saturated soil,then submit a Pilot Study Workplan with the <br /> GE Report Note that all Pilot Study analytical detection hnuts must be sufficiently low to test the <br /> theories proposed in the GE Report and provide comparisons to Water Quality Objectives You will <br /> continue to monitor groundwater during the Pilot Study for the know petroleum.hydrocarbon <br /> 1 contaminants and general parameters(dissolved oxygen,pH,specific conductance,temperature) <br /> 2 If metals of concern(Cry,etc)are detected,or nunerals of concern (SO4,efc)are detected at <br />' potentially harmful levels,then include a Workplan for a Bench Scale Test(BST)with the GE report <br /> The BST should show which contammant(s)are produced and whether the produced contammant(s) <br /> will persist after termination of oxygen infection,using the graphed slope of the declining <br /> contaminant(s) concentrations versus time to calculate a decay rate(time to revert to non-detect) If a <br /> contammant(s)is produced and persistent,provide that information in the BST report for my <br /> evaluation If contaminants)produced are not persistent,provide Workplan for the Pilot Study with <br /> the BST Report containing modifications to the Pilot Study monitoring program, specifically,the <br /> frequency of analyses needed to confirm contaminant decay rates as calculated from BST analytical <br /> evidence <br /> O By 15 December 2004,begin the Pilot Study During the Pilot Study phase,groundwater sampling and <br /> analyses will be conducted,at a mmi num,immediately before startup of the ozone injection system,and <br /> at intervals of one and 2 hours afterwards, in order to validate all contanunant(s)analyses and proposed <br /> 1 I decay rates,if applicable If a BST is not required prior to the Pilot Study, then, at a minimum,analyze <br /> I at least once before and 1 hour after startup of ozone injection <br /> c Install automated data loggers in selected monntonng well(s)to record changes in dissolved oxygen,pH, <br /> j specific conductance, and temperature during the Pilot Study The test data will be helpful to determine <br /> the effectiveness of ozone injection <br /> You may call me at(916) 464-4615 for questions or additional information <br /> LAME <br /> S L BARTON,R G <br /> i <br /> Engineering Geologist <br />] cc Mr Mark Owens,UST Cleanup Fund, SWRCB, Sacramento <br /> Mr Mike Infuma, San Joaquin County Environmental Health Division, Stockton <br /> 1:K.� Jill Tracy,Esq,UNOCAL,Brea <br /> Mr Ben Hennmgburg, ENSR International, Sacramento <br /> Mr Gary Hall, GHH Environmental, Auburn <br /> i <br />' 0 <br /> —I <br />