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DISCUSSION AND CONCLUSIONS <br /> ' As discussed above,the objectives of the SSI, reducing concentrations with time Both analytes <br /> developed in close coordination with the have reached concentrations that are below the <br /> ' PHS/EHD, were to collect the remaining normal reporting limits of 50 and 0 5 ug/L, <br /> additional site data necessary to request site respectively Benzene concentrations have been <br /> closure These data were specifically identified in below the California MCL of 10 ug/L for the last <br /> ' meetings with PHS/EHD and the RWQCB, two sampling events (August 7, 1997 and July 19, <br /> PHS/EHD correspondence, and have been 1999) Analytical data from the July 19, 1999 <br /> documented in HLA work plan addendums and sampling event of all seven wells, and the <br /> .reports(e g , HLA 1997a) Specifically,these data Hydropunch data from HP-2 (depth 4 5 to 7 5 feet <br /> and other requests from PHS/EHD included the bgs) demonstrate that detectable hydrocarbons are <br /> following no longer present in groundwater at the Site <br /> Based on these data there is no measurable free <br /> ' • Additional analytical data to complete product and no TPHg mass remaining in <br /> delineation of the lateral and vertical extent of groundwater at the Site <br /> impacted soil and allow calculation of the <br /> ' contaminant mass in the remaining impacted As discussed above in the Results of Insitu <br /> soil Bioremediation Feasibility Studies Section above, <br /> • Depth-specific groundwater analytical data to the plate count results collected during SSI-Phase <br /> ' allow calculation of the remaining mass of One investigation provide strong evidence that the <br /> dissolved hydrocarbons proposed remedial method for the Site, insitu <br /> 0 Demonstration that free product is not biodegradation, is occurring(Table 4) By <br /> present comparing the magnitude of the HCU populations <br /> MS Site specific physical and chemical data to within similar soil types in impacted-versus <br /> assess the efficacy of remedial measures unimpacted-soils, the HCU population in impacted <br /> ® Analytical data on fuel oxygenates and 1,2- soils is shown to be approximately nearly two <br />' DCA from selected soil and groundwater orders of magnitude higher than in unimpacted <br /> samples, and from a complete final soils This indicates that msitu biodegradation is <br /> groundwater sampling round occurring at the Site This conclusion is further <br />' corroborated by two observations 1)the impacted <br /> These data have all been collected and presented soil contains relatively low TPHg concentrations <br /> in the sections above and are summarized here (1 3 mg/kg), and 2)the magnitude of the total <br />' microbial populations are actually greater in the <br /> The lateral and vertical extent of impacted soil non-impacted sample than the impacted soil <br /> have been assessed and are shown on PIates 4 and sample In addition,the strongest evidence of the <br />' 6 These data and the analytical data on soil efficacy of the proposed remedial measure (insitu <br /> samples within the TPHg soil plume shown on biodegradation) is provided by the decreasing <br /> Plates 4 and 6 were used to estimate the concentration gradient evidenced in Plate 5 and by <br /> contaminant mass remaining in the impacted soil the fact that dissolved hydrocarbons are no longer <br />' These estimates, and the assumptions used, are present onsite at concentrations above normal <br /> presented in the Estimate of Remaining reporting limits <br /> Contaminant Mass Section above The mass of <br />' TPHg in the remaining impacted soils is calculated At the specific request of PHS/EHD, and in <br /> to be approximately 380 kilograms, or 130 gallons compliance with RWQCB policy on oxygenate <br /> of gasoline analytical requirements for site closure, analyses <br />' for the five oxygenates and 1,2-DCA were <br /> Historical and current TPHg and benzene performed on one representative soil and <br /> concentrations in well MW-4(most impacted)are Hydropunch groundwater sample In addition, <br />' shown on Plate 5 The data show a trend of these analyses were performed on groundwater <br /> L 130000087371WPL38737N19 Harding Lawson Associates 21 <br />