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• These borings further defined the general hydrogeology of the site, <br /> of a confined silty, clayey, sand aquifer, overlain by a silty <br /> clay. This aquifer contains a large amount of clay and fine <br /> grained particles and therefore has a low hydraulic conductivity <br /> which probably has slowed the migration of the contamination. <br /> The confined nature of the aquifer and the presence of the gasoline <br /> under the confining clay as evidenced by the SBI at 15 foot sample <br /> makes remediation of the contamination difficult. The lack of <br /> vertical permeability, confining clay layer, and the trapping of <br /> the gasoline beneath the clay present a number of problems : <br /> I. The lack of vertical permeability, greatly slows the <br /> rate of vertical gas exchange effecting a number of <br /> factors: <br /> A. Very low rates of oxygen exchange from the <br /> atmosphere to the aquifer. This slows the action <br /> of aerobic biodegradation which is much faster <br /> than anaerobic biodegradation. <br /> B. Very low rates of carbon dioxide exchange from the <br /> aquifer to the atmosphere, thereby causing a build <br /> up of carbon dioxide in the aquifer inhibiting the <br /> aerobic bacteria. <br /> C. Very low rate of hydrocarbon exchange from the <br /> aquifer to the atmosphere, causing a significant <br /> slowing of gasoline dissipation to the atmosphere. <br /> 2 . Confined aquifer, with gasoline trapped under the <br /> confining clay layer: <br /> A. No permeable vadose zone (dry soil) . This <br /> makes straight vapor extraction impractical <br /> because of the lack of a dry permeable <br /> section of the aquifer from which to extract <br /> the hydrocarbons. Air flow is nearly <br /> impossible through the confining clay. <br /> B. Uneven nature of base of confining clay layer <br /> trapping floating free product. The floating <br /> product trapped in high spots in the aquifer <br /> will not flow towards a pumping well until <br /> the aquifer has been dewatered to below the <br /> base of the clay. <br /> 5 <br />