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By letter to the UST Cleanup Fund dated January 16, 1998, County staff expressed <br /> concern regarding Petitioner's failure to define the extent of affected soil and groundwater and to <br /> document the volume of affected soil excavated at the site. <br /> In March 1998, responding to the County's request for information demonstrating that <br /> natural attenuation was occurring at the site, Petitioner analyzed groundwater samples from site <br /> wells for selected inorganic constituents which are indicative of microbial metabolism of <br /> petroleum hydrocarbons. These analyses, in addition to showing that very active biodegradation <br /> was occurring within the dissolved phase hydrocarbon plume, also showed that in shallow <br /> groundwater, background concentrations of nitrate (about 70 ppm) and Total Dissolved Solids <br /> (1,000 to 1,200 ppm) exceeded State MCLS (45 ppm and 500 ppm respectively). <br /> In January 1999, responding to the County's demand that further delineation of affected <br /> soil and groundwater was required, Petitioner collected soil samples to a depth of 90 feet and <br /> installed two more monitor wells in the vicinity of the release. Analyses of the soil samples <br /> showed that soil affected with TPH-g and BTEX was present in the depth interval of 40 to <br /> 60 feet, that only trace concentrations (less than 0.02 ppm) of toluene and xylene were present at <br /> 70 feet, and that all gasoline constituents were not detectable in the samples from the 80 and <br /> 90 foot depths. Concentrations of MTBE were not detectable in any of the samples collected. <br /> The two new wells were'constructed to monitor groundwater at the depth intervals of <br /> 50 to 60 feet and 85 to 90 feet. These wells, in conjunction with other monitor wells, provided a <br /> means of assessing the vertical hydraulic gradient and the vertical extent of the dissolved phase <br /> hydrocarbon plume at the site. The initial sampling of groundwater from the two new wells <br /> indicated that groundwater at 50 to 60 feet and 85 to 90 below grade had benzene concentrations <br /> of 14,000 ppb and 210 ppb', respectively. The hydraulic gradient between the two zones <br /> monitored was about 0.02 upward. <br /> On May 4, 1999 the County issued a directive requiring Petitioner to submit a workplan <br /> to define the lateral and vertical extent of offsite, down-gradient soil and groundwater <br /> contamination, and to install wells onsite for feasibility studies of viable remedial alternatives. <br /> On.Tune 1999, Petitioner filed a petition pursuant to Health and Safety Code §25297.1 seeking <br /> review of the May 4, 1999 directive and the County's failure to close the site. Petitioner also <br /> ' Concentrations of dissolved phase petroleum hydrocarbons detected in groundwater from this deeper zone are an <br /> artifact of the well installation process, i.e.,contamination introduced at the time the well was being drilled and <br /> constructed. Subsequent sampling, in March and May 1999,have demonstrated a steady decline in the <br /> concentrations of all gasoline constituents. i.e., 150 ppb benzene in March,43 ppb in May. <br /> 7 <br />