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MSDS 19-2 July 1,2002 airborne levels showed tissue anges in the nasal passages. Can be absorbed through the skin in harmful amounts.Recurrent Aspiration may occur during s�allowing or vomiting,resulting in lung overexposure may result in liver and kidney injury. High airborne damage. levels have produced irregular heartbeats in animals and occasional May cause central nervous system depression with headache,stupor, palpitations in humans. Rats exposed to very high airborne levels uncoordinated or strange behavior,or unconsciousness. have exhibited high frequency hearing deficits.The significance of this to man is unknown. Aspiration may occur during swallowing or MICA vomiting,resulting in lung damage. Material may be harmful or fatal Repeated and prolonged overeiposure may lead to chronic lung if swallowed. disease. WARNING:This chemical is known to the State of California to cause MICA COATED WITH TI02 birth defects or other reproductive harm. In a lifetime inhalation test,lun cancers were found in some rats XYLENE exposed to 250 mg/m3 respirabl titanium dust.Analysis of the Increased susceptibility to the effects of this material may be titanium dioxide concentrations in the rat's lungs showed that the observed in people with preexisting disease of any of the following: lung clearance mechanism was overwhelmed and that the results at bone marrow cardiovascular system central nervous system the massive 250 mg/rnr level ar not relevant to the workplace. kidneys liver lungs Repeated and prolonged overexposure may lead to chronic lung Can be absorbed through the skin in harmful amounts. disease. Can irritate or bum eyes. Recurrent overexposure may result in liver and kidney injury. High exposures may produce irregular heart beats. NICKEL,ANTIMONY,TITANIUM YEL W PIGMENT Canada classifies Xylene as a developmental toxin as high exposures Is an IARC,NTP or OSHA carcinTgen. to xylenes in some animal studies have been reported to cause health WARNING:This chemical is knon to the State of California to cause effects on the developing fetus/embryo.These effects were often at cancer. levels toxic to the adult animal.The significance of these effects to humans is not known. Aspiration may occur during swallowing or PETROLEUM NAPHTHA vomiting,resulting in lung damage. Material may be harmful or fatal Laboratory studies with rats hav shown that petroleum distillates if swallowed. Prolonged or repeated skin contact may cause drying, can cause kidney damage and ki ney or liver tumors.These effects cracking,or irritation. were not seen in similar studies ith guinea pigs,dogs,or monkeys. Several studies evaluating petrol um workers have not shown a YELLOW IRON OXIDE significant increase of kidney da age or an increase in kidney or Eye contact may cause any of the following:mechanical irritation liver tumors. PROPYLENE GLYCOL MONOMETHYL HER ACETATE SECTION 4-First Aid Measures May cause eye irritation with disc mfort,tearing,or blurred vision. First Aid Procedures: May cause moderate eye burning. Inhalation: Recurrent overexposure may result in liver and kidney injury. If affected by inhalation of vapor or spray mist,move to fresh air. May cause irritation of the uppernespiratory passages. If not breathing,give artificial respiration,preferably mouth-to-mouth. If breathing difficulty persists,or occurs later, STODDARD SOLVENT consult a physician. The following medical conditions may be aggravated by exposure: Ingestion: asthma skin disorders I In the unlikely event of ingestion,DO NOT INDUCE VOMITING. Call Laboratory studies with rats have khown that petroleum distillates a physician immediately and have names of ingredients available. can cause kidney damage and kidney or liver tumors.These effects Skin or eye: were not seen in similar studies with guinea pigs,dogs,or monkeys. In case of eye contact,immediately Flush with plenty of water for at Several studies evaluating petrole m workers have not shown a least 15 minutes;call a physician.In case of skin contact,wash significant increase of kidney dam ge or an increase in kidney or thoroughly with soap and water.If irritation occurs,contact a liver tumors. physician. TETRAETHYL ORTHOSILICATE SECTION 5-Firefighting Measures Overexposure may causedamage o any of the following organs/systems: kidneys liver I ngs Flash Point(Closed Cup) See Section 11 for exact values. Flammable limits LFL 0.0%UFL 12.8% TITANIUM DIOXIDE Extinguishing media: In a lifetime inhalation test,lung ncers were found in some rats Universal aqueous film-forming foam,carbon dioxide,dry chemical. exposed to 250 mg/n3 respirable anium dust.Analysis of the Fre fighting procedures: titanium dioxide concentrations in he rat's lungs showed that the Full protective equipment,including self-contained breathing lung clearance mechanism was ov rwhelmed and that the results at apparatus,is recommended.Water from fog noales may be used to the massive 250 mg/rrr3 level are n t relevant to the workplace. prevent pressure build-up. Fire&explosion hazards: TOLUENE For flammable liquids,vapor/air will ignite when an ignition source Chromosomal changes in the circul ting blood of exposed workers is present. In other cases,when heated above the flash point,emits have been reported.The significan a of these reports is unclear flammable vapors which,when mixed with air,can burn or be because of exposure to other subst nces. Increased susceptibility to explosive.Fine mists or sprays may be flammable at temperatures the effects of this material may be¢bserved in people with preexisting below the flash point. disease of any of the following: central nervous system kidneys liver respiratory system skin SECTION 6-Accidental Release Measures May cause eye irritation with discomfort,tearing,or blurred vision. 5 MSDS 19-2 July 1,2002 © 2001-2002 E.L du Pont de Ne ours and Company.All rights reserved. Reproduction or translation of any part of this wo beyond that permitted by U.S. copyright laws without thew ' n permission of du Pont is unlawful and strictly forbidden