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MSDS 21 <br /> July 1,2002 <br /> following:mechanical irritation YELLOW IRON OXIDE <br /> STODDARD SOLVENT Eye contact may cause any of the following: mechanical irritation <br /> The following medical condition may be aggravated by exposure: 1,6 HEXAMETHYLENE DIISOCYANATE <br /> asthma skin disorders Repeated overexposure may cause asthma-like reactions with <br /> Laboratory studies with rats hav shown that petroleum distillates shortness of breath,wheezing,cough or permanent lung sensitization. <br /> can cause kidney damage and k ney or liver tumors.These effects The following medical conditions may be aggravated by exposure: <br /> were not seen in similar studies ith guinea pigs,dogs,or monkeys. Individuals with preexisting lung disease, asthma or breathing <br /> Several studies evaluating petrol um workers have not shown a difficulties may have increased susceptibility to the toxicity of <br /> significant increase of kidney da age or an increase in kidney or excessive exposures. Repeated or prolonged skin contact may cause <br /> liver tumors. any of the following:severe irritation burns skin sensitization <br /> TITANIUM DIOXIDE <br /> Eye contact may cause any of the following: burns <br /> In a lifetime inhalation test,lung ncers were found in some rats 2-ETHYLHEXYL ACETATE <br /> exposed to 250-mg/n3 respirabl titanium dust.Analysis of the Ingestion may cause any of the following:gastrointestinal irritation <br /> titanium dioxide concentrations i the rat's lungs showed that the <br /> lung clearance mechanism was o erwheI 'ed and that the results at 2,4-PENTANEDIONE <br /> the massive 250 mg/rrii level are of relevant to the workplace. 2,4-pentanedione, a component of this product,is regulated by the <br /> U.S.EPA,under a significant new use rule.It is a violation of <br /> TOLUENE federal law to sell or use this product in consumer applications, <br /> Chromosomal changes in the circ lating blood of exposed workers including to private individuals,schools,and vocational schools. <br /> have been reported.The significa ce of these reports is unclear Can be absorbed through the skin in harmful amounts. <br /> because of exposure to other sub ances. Increased susceptibility to Repeated exposures to high concentrations has caused adverse health <br /> the effects of this material may b observed in people with preexisting effects in laboratory animals.These effects involved the central <br /> disease of any of the following:c ntral nervous system kidneys nervous system,immune system,and the red blood cell forming <br /> liver respiratory system skin system. No effect was seen at 100 ppm.The odor is disagreeable at <br /> May cause eye irritation with disc mfort,tearing,or blurred vision. a few ppm. Ingestion may result in gastric disturbances. Liquid or <br /> Can be absorbed through the skin in harmful amounts.Recurrent vapor causes irritation,experienced as stinging,excess blinking and <br /> overexposure may result in liver a d kidney injury. High airborne tear production,with excess redness and swelling of the conjunctiva. <br /> levels have produced irregular hea beats in animals and occasional <br /> palpitations in humans. Rats exp ed to very high airbome levels SECTION 4-First Aid Measures <br /> have exhibited high frequency hea ing deficits.The significance of this <br /> to man is unknown. Aspiration may occur during swallowing or First Aid Procedures: <br /> vomiting,resulting in lung damage`Material may be harmful or fatal if Inhalation: <br /> swallowed. I If affected by inhalation of vapor or spray mist,move to fresh air. <br /> WARNING:This chemical is known Ito the State of California to cause If not breathing,give artificial respiration,preferably <br /> birth defects or other reproductive harm. mouth-to-mouth. If breathing difficulty persists, or occurs later, <br /> consult a physician. <br /> VM&P NAPHTHA Ingestion: <br /> Laboratory studies with rats haves own that petroleum distillates In the unlikely event of ingestion,DO NOT INDUCE VOMITING. Call <br /> can cause kidney damage and kidney or liver tumors.These effects a physician immediately and have names of ingredients available. <br /> were not seen in similar studies wit guinea pigs,dogs,or monkeys. Skin or eye: <br /> Several studies evaluating petroleum workers have not shown a In case of eye contact, immediately flush with plenty of water for at <br /> significant increase of kidney dama a or an increase in kidney or least 15 minutes; call a physician.In case of skin contact,wash <br /> liver tumors. thoroughly with soap and water.If irritation occurs,contact a <br /> XYLENE physician. <br /> Increased susceptibility to the effe of this material may be SECTION 5-Firefighting Measures <br /> observed in people with preexisting isease of any of the following: <br /> bone marrow cardiovascular syste central nervous system Rash Point(Closed Cup) See Section 11 for exact values. <br /> kidneys liver lungs Flammable limits LFL 0.0%UFL 13.1 <br /> Can be absorbed through the skin i harmful amounts.Can irritate or Extinguishing media: <br /> burn eyes.Recurrent overexposure ay result in liver and kidney Universal aqueous film-forming foam,carbon dioxide,dry chemical. <br /> injury.High exposures may produce irregular heartbeats.Canada Fire fighting procedures: <br /> classifies Xylene as a developmental toxin as high exposures Full protective equipment,including self-contained breathing <br /> to xylenes in some animal studies h ve been reported to cause health apparatus,is recommended.Water from fog nozzles may be used to <br /> effects on the developing fetus/emb o.These effects were often at prevent pressure build-up. <br /> levels toxic to the adult animal.The ignificance of these effects Fire&explosion hazards: <br /> to humans is not known. Aspiration may occur during swallowing or For flammable liquids,vapor/air will ignite when an ignition source <br /> vomiting,resulting in lung damage. Material may be harmful or fatal is present. In other cases,when heated above the flash point,emits <br /> if swallowed.Prolonged or repeated Skin contact may cause drying, flammable vapors which,when mixed with air,can burn or be <br /> cracking,or irritation. explosive.Fine mists or sprays may be flammable at temperatures <br /> below the flash point. <br /> 7 <br /> MSDS 21 <br /> July 1, 2002 <br /> © 2001-2002 E.I. du Pont de Nem urs and Company.All rights reserved. Reproduction or translation of any part of this <br /> work beyond that permitted by U.S. Copyright laws without the written permission of du Pont is <br /> unlawful and strictly forbidden. <br />