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Diamond Pet Food&Ripon Cogeneration July 12,2013 <br /> Second-Quarter 2013 Groundwater Monitoring Report Page 1 of S <br /> INTRODUCTION <br /> This report presents the results of second-quarter 2013 groundwater monitoring performed by <br /> Lawrence &Associates (L&A) on April 9 and 10, 2013, at Diamond Pet Food Processors of <br /> Ripon California LLC (DP) and Ripon Cogeneration, LLC (Cogen), 942 South Stockton <br /> Avenue, Ripon, California(Figure 1). The work was performed in accordance with Waste <br /> Discharge Requirements (WDR) Order No. R5-2012-0105 for the DP/Cogen site which was <br /> adopted by the California Regional Water Quality Control Board, Central Valley Region <br /> (CVRWQCB) on October 4, 2012. <br /> Second quarter monitoring consisted of measuring the depth to groundwater in monitoring wells <br /> OB-1, OB-2, OB-4, OB-5, OB-7, OB-8, OB-11, OB-17, OB-19, OB-21, OB-22, OB-24, OB-25, <br /> OB-26, and OB-28, on April 9, sampling the wells on April 10, 2013, and analyzing the samples <br /> for pH, electrical conductivity(EC), total dissolved solids (TDS), and nitrate as nitrogen. <br /> Table 1 (following text)presents well descriptions including well names, casing diameter, <br /> reference point elevation, total depth, screened intervals, and aquifer unit(s). <br /> L&A sampled the wells located on the DP/Cogen site. All offsite monitoring, domestic, and <br /> municipal wells were sampled by Stantec for the City of Ripon or Environmental Cost <br /> Management(ECM) for Nestles. Field and laboratory results provided by Stantec and ECM <br /> were used in the preparation of this report and are presented in Attachment A. L&A, however, <br /> did not review the Stantec or ECM sampling methods or data for accuracy. <br /> SECOND-QUARTER 2013 GROUNDWATER MONITORING <br /> FINDINGS <br /> On April 9, 2013, a northeast-southwest trending ridge was present in the semiperched aquifer <br /> in the eastern portion of the DP/Cogen site. The direction of the groundwater gradient in this <br /> area was away from the ridge and ranged between southeast(160°) and northwest(300°) at <br /> magnitudes between 0.000006 and 0.0017 ft/ft. Along the northern and western portions of the <br /> site, the direction of the gradient ranged from northeast(35°)to southwest(225°). Mounding <br /> was present west of the DP/Cogen site in the vicinity of the City of Ripon's waste-water <br /> treatment facility(WWTF)ponds and their fresh-water infiltration pond, and extended eastward <br /> to the western portion of the DP/Cogen site (Table 2; Figure 2). <br /> pH concentrations in all monitoring well samples were within the 6.5 to 8.5 standard pH units <br /> range for DP/Cogen effluent (Table 2). <br /> TDS concentrations in groundwater samples OB-1, OB-4, OB-5, OB-8, OB-11, OB-24, OB-25, <br /> and OB-28 exceeded the 800 mg/L limitation for DP/Cogen effluent. The highest TDS <br /> concentration was measured in well OB-4 (1,800 mg/L) located in the eucalyptus grove in the <br /> northeast quadrant of the site (Figure 3). The lowest TDS concentration was measured in <br /> monitoring well OB-17 (110 mg/L), located in the southeastern corner of the site along the <br /> Stanislaus River. <br /> Nitrate as nitrogen concentrations in wells OB-1, OB-5, OB-7, OB-8, OB-19, OB-26, and OB- <br /> 28 exceeded the 10 mg/L limitation for DP/Cogen effluent. The highest nitrate concentrations <br /> were measured in wells OB-1 (33 mg/L) and OB-28 (31 mg/L; Table 2). <br /> 10107.04 Task 2 Lawrence&Associates <br /> W:I CLIENTSIDiamond Pet Foods 1010107.01-Groundwater Monitoring)Groundwater Monitoring12013 12Q2013 12nd quarter 2013.docx <br />