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Michael Oliphant -2 - 22 March 2012 <br /> Chevron <br /> TRY Offsite-West, Tracy <br /> • TPH affected soil noted at three boring locations in samples obtained at/near the water table <br /> (approximately 18 feet bgs) was analyzed. TPHc was detected at concentrations ranging from <br /> 400 to 810 mg/kg. Ethylbenzene concentrations, ranging from 0.0074 to 7.2 mg/kg, were <br /> detected in three soil samples collected at approximate depths of between 18 and 35 feet bgs. <br /> Benzene, toluene, and xylenes were non-detect (ND) in soil samples collected during the <br /> investigation. <br /> • Polynuclear aromatic hydrocarbon (PAH) compounds were detected in 5 of 22 soil samples <br /> submitted for analysis. AMEC calculated the benzo(a)pyrene toxicity equivalents (BaP TEQs) <br /> for each sample that had at least one carcinogenic PAH (which was chrysene). Chrysene was <br /> detected at concentrations of 0.032 to 0.14 mg/kg in three soil samples at depths between 18 <br /> and 35 feet bgs. The BaP TEQ was determined at 0.005 to 0.023 mg/kg. AMEC reported <br /> these values will be considered in a future human health risk assessment. <br /> • Analytical results from one soil sample collected at 18.5 foot bgs that was submitted for fuel <br /> fingerprint evaluation, indicated that the TPH present resembled weathered San Joaquin Valley <br /> crude oil, considered to be associated with the TAOC crude oil pipelines. <br /> • Two of the offset borings were completed on vacant land to the north, to collect samples for <br /> evaluating groundwater at the downgradient locations. A third water sample was collected for <br /> analysis from one of the other soil borings. <br /> • TPH as diesel (TPHd) and benzene, toluene, ethylbenzene and xylenes (BTEX) were ND for <br /> the samples collected from the two downgradient borings. AMEC concluded that the ND results <br /> define the lateral downgradient extent of affected groundwater. <br /> • Analysis of samples from borings drilled to evaluate deeper groundwater (70 and 90 feet bgs) <br /> reported TPHd concentrations of 130 to 850 micrograms per liter (Ng/L). The results were <br /> denoted as "J" values by the laboratory, which indicate the compound was detected but <br /> determined to be an "approximate" value. Laboratory review of the chromatogram indicates the <br /> TPH is very different from known San Joaquin Valley crude oil, indicating that the TPHd <br /> detections in the deep samples are unrelated to crude oil such as from the historical TAOC <br /> pipelines. <br /> • BTEX compounds were ND for groundwater samples collected during the investigation with the <br /> exception of ethylbenzene at 4.1 pg/L (and 4.3 pg/L for the duplicate), reported in the samples <br /> collected at about 50 feet bgs. <br /> • PAHs at low concentrations were reported in three different water samples, but carcinogenic <br /> compounds were ND, therefore the BaP TEQs were also ND. <br /> • The Report concluded that since the results of the deeper water samples indicated a non-TAOC <br /> pipeline source, the vertical extent of crude oil affected groundwater was defined. <br /> • According to the Report, based on the earlier findings in conjunction with the recent <br /> characterization results, the lateral and vertical extent of affected soil and groundwater has been <br /> delineated and additional investigation was not warranted. <br />