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The results of the five-year COC monitoring event indicate that with the exception of one <br /> chlorinated herbicide (dicamba), no organic COCs were detected in the groundwater and surface <br /> water samples. Since similar concentrations of dicamba were measured in the upstream and <br /> downstream samples, it is believed that the source of the herbicide is from agricultural activities <br /> up-stream of the landfill. Several inorganic COCs were detected in both up-gradient and down- <br /> gradient wells and surface water stations. The similarity in the concentrations in both up- <br /> gradient and down-gradient wells and surface water stations suggest that the inorganic COCs are <br /> naturally occurring and not related to the landfill. As a result, no changes to the current <br /> monitoring program are recommended at this time. <br /> Groundwater quality conditions beneath the Austin Unit during the first quarter 2013 monitoring <br /> period are generally similar to historical results. Non-statistical exceedances for VOCs were <br /> identified at Detection Monitoring Program(DMP)wells AMW-6, AMW-13 and AMW-14. <br /> Trend analyses indicate that statistically significant increasing temporal trends were calculated <br /> for tetrachloroethene and trichloroethene in well AMW-13. These results are similar to previous <br /> results and it has been recommended that wells AMW-6, AMW-13, and AMW-14 be re- <br /> designated as corrective action program(CAP) wells since they have historically contained <br /> VOCs. For the routine inorganic monitoring parameters, CLs were exceeded for constituent <br /> concentrations in DMP wells MW-2A, MW-13, -14,MW-15, and MW-23R. With the <br /> exception of nitrate-N concentrations measured in well MW-14 and sulfate concentrations <br /> measured in well MW-15, there were no statistically significant increasing trends calculated for <br /> the CL exceedances during the current monitoring period. In the CAP wells, trend analyses are <br /> performed instead of comparison to CLs. During the current monitoring period, statistically <br /> significant increasing trends were noted for three VOCs in CAP well AMWA, while decreasing <br /> VOC trends were noted for several VOCs in CAP wells AMWA, AMW-4,AMW-10, and <br /> AMW-11. The increasing trend exhibited for cis-l,2-dichloroethene at well AMW-1 and <br /> generally decreasing (organic and inorganic)trends noted in all of the CAP wells, suggests that <br /> corrective action measures have been successful in reducing facility related groundwater impacts <br /> downgradient of the Austin Unit. <br /> Surface water samples collected from the upstream and downstream surface water monitoring <br /> stations during the first quarter 2013 monitoring period are generally consistent with each other <br /> and no VOCs were detected. These results suggest that landfill operations are not impacting <br /> surface water. <br /> The results of the five-year COC monitoring event indicates that with the exception of one semi- <br /> volatile organic compound(di-n-butyl phthalate), no organic COCs were detected in the <br /> groundwater and surface water samples. It should be noted that phthalates are used as <br /> plasticizers in PVC, which is a common monitoring well material. Therefore,the presence of di- <br /> n-butyl phthalate in well AMW-4 at an estimated trace concentration is believed to be a field <br /> contaminant. Several inorganic CDCs were detected in both up-gradient and down-gradient <br /> wells and surface water stations. The similarity in the concentrations in both up-gradient and <br /> down-gradient wells and surface water stations suggest that the inorganic COCs are naturally <br /> occurring and not related to the landfill. As a result, no changes to the current monitoring <br /> program are recommended at this time. <br /> C A2013-0021\FomardLtr_1Q 13 <br /> -2- <br />