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Andrew Keller <br />-2- <br />20 August 2007 <br />4. The Discharger shall provide a separate section for procedures to be followed in the event <br />of evidence of a release. At a minimum, please include the following: <br />• Definition of evidence of a non -naturally occurring constituent release: <br />- When two non -naturally occurring constituents are above the MDL, or <br />- When one non -naturally occurring constituent is above the PQL. <br />• Notification to the Regional Water Board in the event of evidence of a release: <br />- Immediate verbal notification, and <br />- Certified mail notification within seven days. <br />• Response to a release: Refer the reader to the WDRs Order No. R5-2007-0084 and <br />April 2000 Standard Provisions (Page 14, Section XI et. seq.) for the requirements <br />of a response to a release. Then, provide the Standard Provisions in an appendix. <br />5. Section 3, Sampling Rationale: Please provide revised tables for groundwater, leachate, <br />and stormwater. The revised tables shall include the parameters, analytic method, and <br />sampling schedule. Then, coordinate the table headings in Appendix A to those in Section <br />3. For example, the table header in Section 3 refers to 8015B as an "organic compound" <br />while Appendix A has the heading as a "Total Petroleum Hydrocarbon". These same types <br />of discrepancies are found for "inorganic (dissolved)", "general chemistry", and "organic <br />compounds" listed in Section 3. Attachment A (enclosed) provides an example of the <br />content and format that shall be provided in the tables of Section 3. <br />6. Section 4, Sampling Procedures: High quality chemical data collection is essential in <br />groundwater monitoring and site characterization. The primary limitations to the collection <br />of representative samples include (1) mixing of the stagnant casing and fresh screen <br />waters during insertion of the sampling device; (2) disturbance and re -suspension of settled <br />solids at the bottom of the well when using high pumping rates and raising and lowering the <br />pump and bailer; (3) degassing from the bailer during sample handling and transfer; and <br />(4) introduction of trace organics from the tubing and pump materials of construction. <br />Therefore, the Discharger shall use EPA's "Low -Flow (minimal drawdown) Groundwater <br />Sampling Procedures" (EPA/540/S-95/504, April 1996) for collection of samples. In <br />addition, the Discharger shall prohibit the use of bailers, shall select and define tubing and <br />pump materials to prevent the introduction of organics, and shall define pre -cleaning <br />procedures prior to the use of new tubing, pumps, and collection apparatus. <br />6. Section 6, Quality Assurance/Quality Control: In the SAP, the Discharger shall require the <br />following information for all monitoring data submittals: <br />• The selected laboratory's DHS certification number <br />• The laboratory reports shall be signed by the authorized representative. <br />• The laboratory shall report any "trace" results, each MDL, and each PQL. <br />• The laboratory shall report all QA/QC data required by the WDRs Order <br />No. R5-2007-0084 and April 2000 Standard Provisions. <br />• Then, please refer the reader to the WDRs (Pages 13 through 19) and the April 2000 <br />Standard Provisions for the complete reporting requirements. <br />7. Section 8, Reporting: In the second sentence, please state that the monitoring reports will <br />be in accordance with the WDRs and MRP Order No. R5-2007-0084 and the 2000 April <br />Standard Provisions. <br />