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PANOCHE BURN SITE REMEDIATION <br /> 4. Determining appropriate sampling methods for a tire fire. <br /> 5. Further analysis of the air emissions from a tire fire. <br /> 6. Associated health hazards from the known concentrations of PAHs, dioxins, furans, <br /> volatile and semi-volatile organics, and metals from a tire fire. <br /> Since tire piles are generally composed of tires, these studies should fully characterize the <br /> risks from a tire fire. With this information, more training could be provided to fire <br /> departments and corresponding environmental agencies to better understand the health and <br /> environmental risks, suppression techniques, and remediation methods. <br /> 3.5 Known Hazards <br /> During the fire, the U.S. EPA and state agencies investigated the smoke and burn ash. <br /> Their assessment indicated the ash contained heavy metals, specifically zinc and petroleum <br /> hydrocarbons, while the smoke contained volatile organic compounds and polynuclear <br /> aromatic hydrocarbons (PAHs). Mobile air monitoring by California Air Resources Board <br /> (CARE) indicated the smoke contained low concentrations of the target compounds (e.g., <br /> toluene, benzene, ethyl-benzene, xylenes, styrene, naphthalene, PAHs, total chlorinated <br /> hydrocarbons, and ketones) and elevated levels of benzene. The reported air contaminants <br /> were all below the Occupational Safety and Health Administration (OSHA) Permiss- <br /> ible Exposure Limits (PELs). An earlier U.S. EPA report indicated benzene was 1.5 times <br /> the PEL; however, the U.S. EPA referenced a report from CARB, which indicated the PEL <br /> was 10 times below the actual level (i.e., OSHA PELs is 3.25 mg/m3) as reported in the <br /> CARB laboratory summary table. Appendix N contains further information on the known <br /> hazards of tire fires. <br /> 3.5.1 Health and Safety <br /> To abate the known hazards, the CIWMB required Sukut to assemble a site-specific health <br /> and safety plan that addressed the known hazards. Sukut subcontracted the health and safety <br /> personnel monitoring to SP Environmental Services (SPES). SPEC performed respirator fit <br /> tests, issued personal protective gear, set up and monitored decontamination areas, and <br /> conducted personnel monitoring. In accordance with the health and safety plan, three zones <br /> were established: exclusion zones, contamination reduction zones, and support zones. The <br /> subcontractor conducted air sampling and analysis to determine the extent of hazardous <br /> airborne contaminants introduced during remediation work and to ensure that workers were <br /> properly equipped to keep exposure within acceptable levels. All workers entering the <br /> exclusion zone were required to be in Level C attire. Table 7 summarizes the air monitoring <br /> results for total dust and zinc, and Table 8 provides the results from PAH air sampling. <br /> Appendix E contains the site-specific health and safety plan. The complete air monitoring <br /> report is located in Appendix L. <br /> CIWMB 33 <br />