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sb <br /> congestion in lungs, and bronchopneumonia. Cadmium is a poison that is accumulated <br /> in the liver and kidneys. Thus chronic poisoning leads to liver and kidney damage. <br /> Cigarette smoking and calcium-deficient and diet enhance its toxicity. The absorption <br /> of this metal through the gastrointestinal tract is low. <br /> 4- The OSHA PEL for cadmium is listed as .005 mg/m'. <br /> The Cal/OSHA PEL for cadmium is listed as .005 mg/m'. <br /> The TLV for cadmium is listed as .001 mg/m3. <br /> Chromium <br /> Chromium is a greenish-blue, odorless solid. It is commonly found in the manufacture <br /> of its alloys, such as chrome-steel or chrome-nickel-steel. It is also used for <br /> chromeplating of other metals, for tanning leather, and in catalysts. The toxicity of <br /> chromium alloys and compounds varies significantly. Chromium metal does not exhibit <br /> toxicity. Divalent and trivalent compounds of chromium have a low order of toxicity. <br /> Exposure to the dusts of chromite or ferrochrome alloys may cause lung diseases, <br /> including pneumoconiosis and pulmonary fibrosis. Among all chromium compounds, <br /> only the hexavalent salts are a prime health hazard. Occupational exposure to these <br /> compounds can produce skin ulceration, dermatitis, perforation of the nasal septa, and <br /> kidney damage. The examples of hexavalent salts are the chromates and dichromates of <br /> sodium, potassium and other metals. The water-soluble hexavalent chromium salts are <br /> absorbed into the bloodstream through inhalation. <br /> Chromic acid and its salts have a corrosive action on the skin and mucous membranes. <br /> The lesions are confined to the exposed parts, affecting chiefly the skin of the hands <br /> and forearms and the mucous membranes of the nasal septum. Chromate salts are <br /> human and experimental carcinogens of the lungs, nasal cavity, and Para nasal sinus, <br /> and are also experimental carcinogens of the stomach and larynx. Hexavalent <br /> compounds are more toxic than trivalent. Exposure to chromium has been associated <br /> with lung changes in workers exposed to chromium alloys. Chromium dust exposure <br /> may cause minor lung changes. <br /> The OSHA PEL is listed as 0.1 mg/m' for chromic acid (Cr[VI)), 0.5 mg/m' for <br /> Cr(III) compounds, and 1.0 mg/m' for chromium as a metal. <br /> The Cal/OSHA PEL is listed as 0.01 mg/m' for insoluble Cr(VI) compounds, and <br /> 0.5 mg/m' for other forms. <br /> 1 The TLV is listed as 0.01 mg/m' for insoluble Cr(VI) compounds, 0.05 mg/m' for <br /> soluble compounds, and 0.5 mg/m' for other forms. <br /> WARNING: Chromium is known to the State of California to cause cancer. <br /> sb Environmental Services.LLC O October,2003 California Integrated Waste Management Board <br /> Site Specific Health and Safety Plan Page 12 of 62 Tracy Tire Fire Remediation Project <br />