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was analyzed using GC/MS. Low concentrations of toluene, benzene, xylenes, and <br /> limonene were detected. More extensive GC/MS analysis also showed alkanes, substituted <br /> benzenes, substituted hydrazines, ketones, halogenated hydrocarbons, substituted phenols, <br /> nitriles, benzoic acids, and substituted benzene amines. Several PAHs were also detected <br /> including anthracene, pyrene, naphthalene, and fluoranthene. An Ames test for <br /> mutagenicity of the tire residue showed positive mutagenic activity. <br /> 2.4.2 Somerset, Wisconsin Tire Fire <br /> Stofferahn and Simon (1987) present an overview of events surrounding a tire fire <br /> that began on October 13, 1986 near Somerset, Wisconsin. Approximately six million tires <br /> were consumed out of an estimated eight to nine million scrap tire stockpile. The stockpile <br /> occupied about 6 hectare (15 acres) on a 10 hectare (25 acres) property. The smoke plume <br /> was visible for "several miles downwind." An intense fire raged for three days, after which <br /> it subsided and the threat of the fire spreading off-site was eliminated. The fire burned <br /> itself out after a period of approximately two weeks. <br /> A trailer park was approximately 0.8 km (one-half mile) north of the yard fence line. <br /> At the initial stage of the incident, a thick black smoke plume entered the park. Officials <br /> in charge decided to evacuate the trailer park, since the nature of potential health threats <br /> resulting from exposure to such a plume were not known. The evacuation remained in <br /> effect for one day, after which shifting wind patterns eliminated the heavy exposures that <br /> occurred on the first day. <br /> Recommendations to the general public were broadcast via local radio stations: <br /> • Those experiencing discomfort from the smoke should evacuate the area <br /> impacted by the plume or stay indoors in a sealed residence; and <br /> • Outdoor items with which people might come into contact on a routine basis <br /> (e.g., autos, laundry, outdoor furniture) or that would be ingested (e.g., <br /> garden vegetables) should be washed thoroughly. <br /> Air monitoring conducted by the US EPA Emergency Response Team (ERT) <br /> indicated a concentration of total suspended particulate (TSP) exceeding the 260 µg/m3 <br /> primary National Ambient Air Quality Standard (NAAQS) in effect at that time. The ERT <br /> also concluded that the smoke became visible at about 250 pg/m3 TSP. The rough <br /> correlation to the primary standard resulted in the recommendation to response personnel <br /> to don respiratory protection or to avoid areas where the smoke plume was visible. No <br /> details on the method of sampling or analysis were given. <br /> Air samples collected by the Wisconsin Department of Natural Resources (WDNR) <br /> were analyzed for concentrations of total coal tar pitch volatiles (CTPV). At times, these <br /> concentrations exceeded the threshold limit value time-weighted average (TLV-TWA) of 0.2 <br /> Mg/M3. <br /> The authors compared the air concentration levels measured by the ERT and <br /> WDNR at the Somerset site with concentrations reported at two other major tire fires, the <br /> 18 <br />