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I <br /> I <br /> . During first quarter 2003 (between January 9, 2003 and March 17, 2003), Stratus technician conducted <br /> eleven site visits to collect field parameters and laboratory parameters. Field data sheets presenting field <br /> parameters collected between January 9, 2003 and March 17, 2003 are included in Appendix A, and <br /> certified analytical reports with chain-of-custody documentation are included in Appendix C. <br /> On March 17, 2003, the ozone injection system was observed non-functional. Based on hour meter <br /> readings recorded for March 11 and March 17, 2003, the C-Sparge'"" system likely shutdown on March <br /> 12, 2003. On March 17, 2003, upon identifying that there was no power supply to the C-SpargeTM system, <br /> Stratus technician's attempt to re-start the system by re-setting the power supply and was not successful. <br /> Stratus in co-ordination with C-Sparge'"' panel manufacturer (KVA®) identified the problem to be <br /> associated with a solenoid valve. The ozone injection will be re-started after replacing the solenoid valve <br /> during the second quarter 2003. <br /> Monitoring Plan <br /> Monitoring wells MW-3 through MW-10 are used as observation wells to monitor the performance of <br /> ozone injection system. Monitoring wells MW-1 and MW-2 are used as background wells to evaluate and <br /> monitor for natural geo-chemical changes in groundwater. The following field and laboratory parameters <br /> will be monitored periodically to evaluate and optimize the performance of the ozone injection system. <br /> Field Parameters: pH, Dissolved Oxygen (DO), and Specific Conductivity <br /> Laboratory Parameters: TPHG, BTEX, Chemical Oxygen Demand (COD), Ferrous Iron, Total Organic <br /> Carbon (TOC), DO, and Oxidation Reduction Potential (ORP) <br /> During first quarter 2003, field parameters were collected on a weekly basis and laboratory parameters <br /> 0 were collected on a monthly basis. Beginning second quarter 2003, the sampling frequency for field <br /> parameters will be changed to bi-monthly and the sampling frequency for laboratory parameters will be <br /> changed to quarterly. TPHG, BTEX, and oxygenates will also be analyzed as a part of regular quarterly <br /> monitoring program. Table 3 presents the revised sampling frequency, field and laboratory parameters <br /> analyzed, and significance of both lab& field parameters. <br /> Under the ozone injection monitoring plan, groundwater samples for laboratory analysis were collected <br /> without purging. However, groundwater monitoring samples collected as part of the quarterly monitoring <br /> program (including the wells listed as observation wells)were collected after purging. <br /> Results <br /> Results of field and analytical parameters collected to date to evaluate and optimize the performance of <br /> ozone injection system are presented in Tables 4 and 5. <br /> Field Parameters <br /> pH <br /> Prior to the C-Sparge'"" system start-up (December 11, 2002), pH measured in onsite monitoring wells <br /> (MW-1 through MW-10) were in the range of 6.20 to 7.4. During the operation of ozone injection system <br /> (between January 9 and March 17, 2003), pH levels in onsite monitoring wells were in the range of 6.28 to <br /> 10.14. A consistent trend of pH variation either correlating to petroleum hydrocarbon concentrations or to <br /> natural variation (observed in background monitoring wells)could not be identified. <br /> PA1Bp-Arco for URS154691Quartcrly120031Arco_5469_1 Q03.doc 57RATV5 <br />