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Dissolved Oxygen (DO) <br /> DO levels in the onsite monitoring wells prior to system start-up, measured using a field instrument on <br /> December 11, 2002, were in the range of 0.6 mg/L (MW-6) to 3.3 mg/L (MW-7). The DO levels from the <br /> laboratory analysis of groundwater samples collected on December 23, 2003 were in the range of 1.75 <br /> mg/L to 4.69 mg/L. The difference in DO observed between the field instrument readings and the <br /> laboratory results is probably due to aeration of samples during purging and handling of samples collected <br /> for laboratory analysis. The field instrument used to measure DO is a down-hole (in-well) probe and is <br /> considered representative of field conditions. <br /> After the system start-up, DO levels in observation wells measured using a field instrument were in the <br /> range of 0.1 mg/L to 11.6 mg/L. During first quarter 2003, the DO levels increased to more than 10 mg/L <br /> in observation wells MW-7 and MW-9 located within 15 feet of injection points and to more than 4 mg/L in <br /> observation well MW-5 located within 20 feet of injection point. A significant increase on the order of <br /> 200% and 300% in DO levels was observed in monitoring wells MW-5, MW-7, and MW-9. <br /> In addition to the field instrument measurements for DO, groundwater samples were collected and <br /> forwarded for laboratory analysis. The DO levels in groundwater samples analyzed by laboratory during <br /> the first quarter 2003 were in the range of less than 1 mg/L to 12.4 mg/L. <br /> Based on DO levels measured both by field instrument and laboratory analysis, it appears that a minimum <br /> radius of influence of 18 feet has been established by the ozone injection system. <br /> Specific Conductivity <br /> The average specific conductivity measured in onsite monitoring wells during ozone injection is either less <br /> than, or close to, the levels measured prior to ozone injection. <br /> Laboratory Parameters <br /> Chemical Oxygen Demand(COD) <br /> The COD concentrations varied from less than laboratory detection limits (<30 mg/L) to 60 mg/L in the <br /> groundwater samples collected prior to start-up (December 23, 2002) of ozone injection system. <br /> Analytical results of groundwater samples collected on January 14 and February 12, 2003 (during <br /> operation of C-Sparge System) indicate that the COD concentrations varied from less than laboratory <br /> limits to 190 mg/L. A consistent correlation of higher COD concentration at monitoring wells with higher <br /> petroleum hydrocarbon concentrations has been observed in data collected from monitoring wells MW-4, <br /> MW-5, MW-6, and MW-S. <br /> Oxidation Reduction Potential(ORP) <br /> ORP in groundwater samples collected from onsite monitoring wells on January 14 and February 12, <br /> 2003, were in the range of 310 millivolt (mv) to 630 mv. This range of ORP generally falls in the category <br /> of an oxidizing environment. <br /> Ferrous Iron <br /> The ferrous iron concentration in groundwater samples collected from select monitoring wells on <br /> December 23, 2002, were in the range of less than 0.1 mg/L to 3.9 mg/L. The ferrous concentrations in <br /> groundwater samples collected on January 14 and February 12, 2003, varied from less than 0.10 mg/L to <br /> 0.69 mg/L. <br /> P A1Bp-Arco for URS154691Quarterly\20031Arco_5469_1 Q03.doe 5 TRA TU,,5 <br />