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and maintenance of the ozone injection system. The hour meter of the ozone injection system was <br /> observed as non-functional during the site visits conducted during the first quarter and was replaced on <br /> May 5, 2004. Field data sheets presenting field parameters collected between April 5, 2004 and June 28, <br /> 2004 are included in Appendix A, and certified analytical reports with chain-of-custody documentation are <br /> included in Appendix C. Analytical data were submitted to the State Water Resources Control Board as <br /> required by AB2886. The electronic delivery receipt is attached in Appendix C. <br /> Ozone Iniection Monitoring Plan <br /> Monitoring wells MW-3 through MW-10 are used as observation wells to monitor the performance of the <br /> ozone injection system. Monitoring wells MW-1 and MW-2 are used as background wells to evaluate and <br /> monitor for natural geo-chemical changes in the groundwater. <br /> During the second quarter 2004, field parameters were collected on a monthly basis and select laboratory <br /> parameters were collected on a quarterly basis. During the second quarter 2004 monitoring event, all <br /> samples were collected after purging three volumes of well casing. The modified ozone injection <br /> monitoring plan is listed below and a summary of frequency and significance of field and laboratory <br /> parameters is presented in Table 3. <br /> Field Parameters (Monthly): pH, Dissolved Oxygen (DO), and Specific Conductivity <br /> Laboratory Parameters (Quarterly): GRO, BTEX, five oxygenates, Chemical Oxygen Demand (COD), <br /> Ferrous Iron, Total Iron, and Heterotrophic Plate Count. <br /> Laboratory Parameters (Annually): Total Organic Carbon (TOC), Nitrates, Sulfates, Phosphates, and Total <br /> Dissolved Solids. <br /> Results <br /> Results of field and analytical parameters collected to date to evaluate and optimize the performance of <br /> the ozone injection system are presented in Tables 4 and 5. The GRO, benzene, and MTBE <br /> concentrations observed in all the groundwater monitoring wells during the second quarter 2004 are <br /> presented in Figure 4. Change in DO concentrations for select observation and background monitoring <br /> wells are presented in Figure 5. The historical GRO, benzene, and MTBE concentration variation over <br /> time at select monitoring wells (MW-4 through MW-8) are illustrated graphically in Figures 6 through 10. <br /> GRO concentrations have decreased in the groundwater samples collected from MW-4, MW-5, MW-6, <br /> and MW-8 since the previous sampling event (March 4, 2004). The greatest decrease of GRO (from <br /> 15,000 µg/L to 180 Ag/L) was reported in the sample collected from MW-8. The concentration of GRO <br /> reported for the groundwater sample collected from well MW-5 was due to a discrete peak at C5 <br /> indicating presence of MTBE only. The GRO concentrations continue to be lower than the historical high <br /> concentrations and appear to be decreasing. <br /> During the second quarter 2004, benzene concentrations followed a decreasing trend similar to that of <br /> GRO since the previous sampling event (March 4, 2004). Benzene was reported in samples collected <br /> from wells MW-4 and MW-8 at concentrations of 1,900 µglL and 990 µg/L, respectively. The highest <br /> decrease in benzene concentration from 3,100 µg/L (March 4, 2004) to 990 µglL was observed in well <br /> MW-8. <br /> Since the previous sampling event, MTBE concentrations appear to have decreased in groundwater <br /> samples collected from wells MW-1, MW-4, MW-5, and MW-6, while an increase in concentrations was <br /> observed in groundwater samples collected from wells MW-8, MW-9, and MW-10. The greatest decrease <br /> in MTBE concentration (from 37,000 pg/L to 15,000 pg/L) was observed in well MW-6, while the greatest <br /> increase (from 31,000 µglL to 32,000 pg/L) was observed in well MW-8. <br /> PAHp-Arco for URS154691Quarterly120041Arco_5469_2Q04,doe 5TI'ATU5 <br />