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Ms. Anne P. Conner 3 10/9/2007 <br /> Pacific Gas&Electric Company <br /> conducted beneath Pond 3. Ponds 1, 2 and 3 were backfilled, graded, and vegetated with <br /> native vegetation (PG&E, 2006). WDR 96-176 was issued less than two years later in <br /> 1996. <br /> 1.2 Purpose and Objectives <br /> The objective of the proposed scope of work is to establish whether chemicals exist <br /> beneath Pond 3 that are associated with drilling and production fluids and that are also <br /> included in the Monitoring and Reporting Program of WDR 96-176 (MRP). Currently, <br /> groundwater monitoring wells are located around the perimeter of Pond 3; however, no <br /> monitoring wells exist within Pond 3 (Figure 1-2). Furthermore, there are no historical <br /> records of either soil or groundwater sampling within the Pond 3 footprint except for soil <br /> excavation limit sampling that was conducted to verify that the pond could be closed. <br /> Site conditions and the groundwater monitoring program were recently reassessed based <br /> on a supplemental groundwater and surface water sampling program and a series of <br /> hydrogeological, statistical and geochemical evaluations on the sampling data (MSE, <br /> 2007a). The groundwater monitoring program evaluation concluded that groundwater <br /> was most likely not currently affected by chemicals associated with drilling materials <br /> historically disposed in Pond 3. However, data were not collected to assess groundwater <br /> and soil conditions directly beneath Pond 3. <br /> The current scope of work will therefore focus on site characterization beneath Pond 3 to <br /> establish 1) whether there are elevated concentrations of chemicals associated with <br /> drilling and production fluids that are also included in the MRP, and 2) whether Pond 3 <br /> might be a source of these chemicals, and if so, to what extent this source has affected <br /> the surrounding area. <br /> 1.3 Site Geologic, Hydrologic, and Hydrogeologic Conditions <br /> The upper soils at McDonald Island consist of peats and muds originating from tidal <br /> wetlands. Dredging activities and periodic flooding of the island have also deposited <br /> sands, silts, and clays along the near surface perimeter of the island. These two basic <br /> soil types are thought to constitute the bottom of the former surface impoundments and <br /> impoundment berms. The remaining soils in the vicinity of the surface impoundments are <br /> characterized as poorly drained with low-to-rapid permeability. The berm fill, which <br /> mantles most of the pond site, is up to 14 feet thick and consists of intermixed silts, sandy <br /> silts, clayey silts, silty sands, and sands (RWQCB, 1996). <br /> Depth to groundwater in the vicinity of the surface impoundments ranges from 4 to 14 <br /> feet, depending on location, surface elevation and season. Boring logs indicate that clays <br /> and interbedded sands underlying the surface impoundments are saturated and that <br /> groundwater beneath the site occurs under unconfined conditions. <br /> Previous investigations indicated that there is generally no consistent groundwater flow <br /> direction in the shallow aquifer around Pond 3 (MSE, 2007a). This is supported by <br /> historical groundwater elevation data that demonstrate that hydrologic and hydrogeologic <br /> conditions at the site are very complex. Small changes in these conditions are sufficient <br /> to substantially alter flow direction and velocity. These changes apparently occur from <br /> random events such as irrigation, precipitation, evapotranspiration and groundwater and <br /> surface water extraction. <br />