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EPA Method 1613
<br />PCDD/F
<br />FAL ID: 11472-004-SA Date Extracted: 04-30-2018 ICal: PCDDFAL4-12-20-17 Acquired: 05-02-2018
<br />Client ID: SP5-4 Date Received: 04-13-2018 GC Column: DB5MS 2005 WHO TEQ: 0.539
<br />Matrix: Solid Amount: 5.01 g Units: pg/g Basis: Dry Weight
<br />Batch No: X4493 % Solids: 91.50
<br />Compound Conc DL Qual
<br />2005
<br />WHO Tox MDL Compound Conc DL Qual
<br />2,3,7,8-TCDD ND 0.193 - 0.0273
<br />1,2,3,7,8-PeCDD ND 0.231 -0.0570
<br />1,2,3,4,7,8-HxCDD 0.441 - J 0.0441 0.0793
<br />1,2,3,6,7,8-HxCDD 0.971 - J 0.0971 0.0940 Total TCDD ND 0.193
<br />1,2,3,7,8,9-HxCDD 0.806 - J 0.0806 0.0823 Total PeCDD 2.34 -J
<br />1,2,3,4,6,7,8-HpCDD 15.6 -0.156 0.0842 Total HxCDD 10.1 -
<br />OCDD 90.0 - 0.0270 0.172 Total HpCDD 30.6 -
<br />2,3,7,8-TCDF ND 0.226 -0.0269
<br />1,2,3,7,8-PeCDF ND 0.191 -0.0449
<br />2,3,4,7,8-PeCDF 0.324 - J 0.0972 0.0468
<br />1,2,3,4,7,8-HxCDF ND 0.289 -0.0437
<br />1,2,3,6,7,8-HxCDF ND 0.266 - 0.0417
<br />2,3,4,6,7,8-HxCDF ND 0.283 - 0.0574
<br />1,2,3,7,8,9-HxCDF ND 0.344 -0.0657 Total TCDF 0.380 -J
<br />1,2,3,4,6,7,8-HpCDF 3.07 - J 0.0307 0.0747 Total PeCDF 1.62 -J
<br />1,2,3,4,7,8,9-HpCDF 0.399 - J 0.00399 0.0883 Total HxCDF 3.21 -J
<br />OCDF 6.79 - J 0.00204 0.170 Total HpCDF 9.66 -
<br />Internal Standards % Rec QC Limits Qual
<br />13C-2,3,7,8-TCDD 81.6 25.0 - 164
<br />13C-1,2,3,7,8-PeCDD 89.8 25.0 - 181
<br />13C-1,2,3,4,7,8-HxCDD 110 32.0 - 141
<br />13C-1,2,3,6,7,8-HxCDD 108 28.0 - 130
<br />13C-1,2,3,4,6,7,8-HpCDD 95.1 23.0 - 140
<br />13C-OCDD 90.6 17.0 - 157
<br />13C-2,3,7,8-TCDF 79.4 24.0 - 169
<br />13C-1,2,3,7,8-PeCDF 95.8 24.0 - 185
<br />13C-2,3,4,7,8-PeCDF 95.5 21.0 - 178
<br />13C-1,2,3,4,7,8-HxCDF 97.0 26.0 - 152
<br />13C-1,2,3,6,7,8-HxCDF 94.2 26.0 - 123
<br />13C-2,3,4,6,7,8-HxCDF 94.8 28.0 - 136
<br />13C-1,2,3,7,8,9-HxCDF 85.5 29.0 - 147
<br />13C-1,2,3,4,6,7,8-HpCDF 79.6 28.0 - 143
<br />13C-1,2,3,4,7,8,9-HpCDF 80.0 26.0 - 138
<br />13C-OCDF 87.1 17.0 - 157
<br />Cleanup Surrogate
<br />37Cl-2,3,7,8-TCDD 73.4 35.0 - 197
<br />Analyst:Reviewed By:
<br />Date:Date:
<br />A Isotopic Labeled Standard outside QC range but
<br />signal to noise ratio is >10:1
<br />B Analyte is present in Method Blank
<br />C Chemical Interference
<br />D Presence of Diphenyl Ethers
<br />DNQ Analyte concentration is below calibration range
<br />E Analyte concentration is above calibration range
<br />F Analyte confirmation on secondary column
<br />J Analyte concentration is below calibration range
<br />M Maximum possible concentration
<br />ND Analyte Not Detected at Detection Limit Level
<br />NP Not Provided
<br />P Pre-filtered through a Whatman 0.7um GF/F filter
<br />S Sample acceptance criteria not met
<br />X Matrix interferences
<br />* Result taken from dilution or reinjection
<br />5/2/2018 5/2/2018
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