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11 <br />Section 5 Fire and Explosion Hazard lliforrnation <br />(,Continue <br />Special Protective Equipment and Precautions for Fire Fighters: Self-contained MSHA/NIOSH approved respiratory protection and full protective <br />clothing should be worn when fumes and/or smoke from fire are present. Heat and Flames cause emittance of acrid smoke <br />and fumes. DO NOT RELEASE <br />RUNOFF FROM FIRE CONTROL METHODS TO SEWERS OR WATERWAYS. <br />Hazardous Material Identification System (HMIS) Classification <br />National Fire Protection Associate <br />(NFPA) <br />0 No significant risk to health <br />0 Materials that will not burn <br />Materials that are normally stable, even <br />%0 <br />41 > <br />under fire conditions, and will not react <br />with water, polymerize, decompose, <br />condense, or self -react. Non -explosive. <br />HEALTH = 0, No Hazard beyond that of ordinary <br />combustible materials. <br />FIRE = 0, Materials that will not burn <br />INSTABILITY = 0, Normally stable, even <br />under fire exposure conditions, <br />and are not reactive with water. <br />Section b.% "'= = Accidental <br />R'elease:P1leasures <br />Personal Precautions, Protective Equipment and Emergency Procedures: Not applicable to nickel alloy in solid state. <br />For spills involving finely divided <br />particles, clean-up personnel should be protected against contact with eyes and <br />skin. Collect material in appropriate, labeled <br />containers for recovery or <br />disposal in accordance with federal, state, and local regulations. <br />Environmental precautions: Not applicable to steel in solid state. Follow applicable federal, state, and local regulations. <br />Methods and materials for containment and clean up: Collect material in appropriate, labeled containers for recovery <br />or disposal in accordance with <br />federal, state, and local regulations. Follow applicable OSHA regulations (29 CFR 1910.120) and all other pertinent state and federal requirements. <br />Section 7 Handlin <br />` and Storage <br />Precautions for safe handling: Operations with the potential for generating concentrations above 1/2 the PEL of airborne particulates should be evaluated <br />and controlled as necessary. Practice good housekeeping. Avoid breathing metal fumes and/or dust. <br />Conditions for safe storage, including any incompatibilities: Store away from <br />acids and incompatible materials. <br />Section 8 Exposure Controls / Personal <br />Protection <br />Component <br />CAS # <br />% wen htl <br />OSHA PEL-TWA <br />ACGIH TLV -TWA <br />Iroon <br />. <br />100 mg/m3 <br />5.0 mg/m3 ; A42 <br />[I oxide] <br />(Fe) 7439-89-6 <br />60 88 <br />[fume] <br />[dust &fume] <br />Alloying Elements <br />1.0 mg/m3 [metal] <br />0.5 mg/m3; A4 <br />[metal & Cr (III)] <br />0.5 mg/m3 [Cr (III)] <br />Chromium3 <br />(Cr) <br />7440-47-3 <br />10-30 <br />0.05 mg/m3 • A1;BE1 <br />(Metal) <br />3 <br />5.0 µg/m (Cr (V!)] <br />[Water <br />-Soluble Cr (VI) compounds] <br />2.5 µg/nn3 [Cr (VI)] <br />0.01 nng/m3 ; A2 <br />Action Level <br />[Insoluble Cr (VI) compounds] <br />1.5 mg/m3 ; A5 <br />0.5 mg/m3 [metal] <br />[elemental] <br />Nicke13 <br />Ni <br />( ) <br />7440-02-0 <br />0 - 46 <br />3 <br />0.1 nng/m [Insoluble <br />0.2 mg/m3 ; Al <br />(Metal) <br />[Insoluble compounds] <br />compounds] <br />0.1 mg/mg3 ; Al <br />Nickel subsulfide <br />0.02 mg/m3 ; A4 <br />Manganese <br />0.2 mg/m3 [respirable fraction] <br />[respirable fraction] <br />[elemental & inorganic cpds] <br />(Mn) <br />7439-96-5 <br />0 - 15 <br />3 mg/m3STEL <br />3 <br />0.1 mg/m ; A4 <br />Inhalable fraction <br />10.0 mg/m3 <br />10.0 mg/m3 [total dust] <br />[inhalable] <br />Molybdenum <br />(Mo) <br />7439-98-7 <br />< 8 <br />3.0 mg/m3 [respirable] <br />3.0 mg/m3 <br />[respirable] <br />0.2 mg/m3 <br />0.1 mg/m3 [fume] <br />[fume] <br />Copper3 <br />(Cu) <br />7440-50-8 <br />< 6 <br />1.0 mg/n13 [dust & mist) <br />1.0 mg/m3 <br />dust & mist <br />Titanium3 <br />(Ti) <br />13463-67-7 <br />< 6 <br />15.0 mg/m3 [total dust] <br />10 mg/m3 ; A4 <br />[metal & dioxide] <br />[dust] <br />Carbon <br />(C) <br />744044-0 <br />< 2 <br />N/A <br />N/A <br />Rev. Date May - 2015 4 PSM -SDS -SS <br />