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DFI200 cis-DICHLOROETHYLENE <br />1152 <br />to air. Potentially explosive reaction with chlorotrifluoro- <br />ethylene at 180°C. Reaction with ozone forms dangerous <br />products. Explosive reaction with perchloryl fluoride when <br />heated above 100°C. Also can explode spontaneously. Re- <br />acts violently with chlorosulfonic acid; HNO3; oleum. Can <br />react vigorously with oxidizing materials. To fight fire, <br />use alcohol foam, CO2 , thy chemical. When heated to de- <br />composition it emits toxic fumes of Cr. <br />DFI200 <br />HR: <br />cis-DICHLOROETHYLENE <br />CAS: 156-59-2 <br /> <br />NIOSH: KY 9420000 <br />mf: C2H2C12 mw: 96.94 <br />HCC1HCI <br />PROP: Colorless liquid, pleasant odor. Mp: —80.5°, bp: <br />59°, lel: 9.7%, uel: 12.8%, flash p: 39°F, d: 1.2743 @ <br />25°/4°, vap press: 400 mm @ 41.0°, vap d: 3.34. <br />SYN: I.2-DICHLOROETHYLENE <br />TOXICITY DATA: <br />mmo-smc 100 nunon <br />nruna-smc 40 nunol/L <br />mrc-smc 100 mmoUL <br />dns-rat:lvr 4300 p.moUL <br />ihl-mus LCLo:65000 mg/ <br />m3/2 H <br />ihl-cat LCLo:20000 mg/ <br />m3/6H <br />Reported in EPA TSCA Inventory. <br />THR: Mildly toxic by by ingestion and inhalation. In high <br />concentration it is irritating and narcotic. Has produced <br />liver and kidney injury in experimental animals. A sus- <br />pected carcinogen. Mutagenic data. Sometimes thought to <br />be nonflammable, however, it is a dangerous fire hazard <br />when exposed to heat or flame. Reaction with solid caustic <br />alkalies or their concentrated solutions produces chloracet- <br />ylene gas which ignites spontaneously in air. Reacts vio- <br />lently with N204; KOH; Na; NaOH. Moderate explosion <br />hazard in the form of vapor when exposed to flame. Can <br />react vigorously with oxidizing materials. To fight fire, <br />use water spray, foam, CO2 , dry chemical. When heated <br />to decomposition it emits toxic fumes of Cr. See also <br />1,1-DICHLOROETHYLENE and CHLORINATED HY- <br />DROCARBONS, ALIPHATIC. For further information, <br />see Vol. 4, No. 3 of DPIM Report. <br />DFI600 HR: 1 <br />trans-1,2-DICHLOROETHYLENE <br />CAS: 156-60-5 NIOSH: KY 9400000 <br />C2H2C12 mw: 96.94 <br />PROP: Flash p: 35.6°F, lel: 9.7%, uel: 12.8%. <br />SYN: <br />trans-ACETYLENE DICHLORIDE trans-DICHLOROETHYLENE <br />TOXICITY DATA: CODEN: <br />ihl-hmn TCLo:4800 mg/m3/1 0M AHBAAM 116,131,36 <br />ipr-rat LD50:7536 mg/kg TXCYAC 7,141,77 <br />ihl-mus LCLo:75000 mg/m3/2H AHBAAM 116,131,36 <br />ipr-mus LD50:4019 mg/kg TXCYAC 7,141,77 <br />ihl-cat LCLo:43000 mg/m3/6H <br />AHBAAM 116,131,36 <br />Reported in EPA TSCA Inventory. <br />THR: Mildly toxic to humans by inhalation. Mildly toxic <br />experimentally by inhalation and intraperitoneal routes. A <br />very dangerous fire hazard when exposed to heat or flame. <br />Violent reaction with difluoromethylene dihypofluorite. <br />Forms shock-sensitive explosive mixtures with dinitrogen <br />tetraoxide. Reaction with solid caustic alkalies or their con- <br />centrated solutions produces chloracetylene gas which ig- <br />nites spontaneously in air. Reacts violently with N,04; <br />KOH; Na; NaOH. Moderate explosion hazard in the form <br />of vapor when exposed to flame. Can react vigorously with <br />oxidizing materials. To fight fire, use water spray, foam, <br />CO2 , dry chemical. When heated to decomposition it emits <br />toxic fumes of Cr. See also 1,1-DICHLOROETHYLENE <br />and CHLORINATED HYDROCARBONS, ALIPHATIC. <br />For further information, see Vol. 4, No. 3 of DPIM Report. <br />DFI800 HR: 3 <br />1,2-DICHLOROETHYLENE CARBONATE <br />CAS: 3967-55-3 NIOSH: JH 7400000 <br />ml: C3H2C1203 mw: 156.95 <br />SYN: 4.5-DICHLOR0-2-0X0-1.3-DIOXOLANE <br />TOXICITY DATA: CODEN: <br />scu-mus TDLo:648 mg/kg/54W- JNCIAM 48,1431,72 <br />: ETA <br />THR: An experimental tumorigen. When heated to decom- <br />position it emits toxic fumes of Cr. <br />DFJ000 HR: 3 <br />DICHLORO(ETHYLENEDIAMMINE)PLATINUM(II) <br />CAS: 14096-51-6 NIOSH: TP 2497100 <br />nil: C2H8C12N2Pt mw: 326.11 <br />SYNS: <br />ETHYLENEDIAMINEDICHLORIDE PLATINUM ETHYLENEDIAMMINE <br />PLATINUM (H) <br />DICHLORIDE <br />TOXICITY DATA: CODEN: <br />mmo-sat 2 g/plate MUREAV 77,45,80 <br />mma-sat 2 µ,g/plate MUREAV 77,45,80 <br />dnd-esc 100 mmol/L <br />CBINA8 16,39,77 <br />dni-lunn:oth 25 iLmol/L <br />UCNAW 6,207,70 <br />oms-rnam:lym 10 µ,moUL <br />BCPCA6 23,1659,74 <br />ipr-mus LDLo:14 mg/kg BCPCA6 2,187,73 <br />THR: Poison by intraperitoneal route. Human mutagenic <br />data. See also PLATINUM COMPOUNDS. When heated <br />to decomposition it emits very toxic fumes of a- and <br />NOR. <br />CODEN: <br />TCMUD8 4,365,84 <br />TCMUD8 4,365,84 <br />TCMUD8 4,365,84 <br />CRNGDP 5,1629,84 <br />AHBAAM 116,131,36 <br />AHBAAM 116,131,36