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T1N000 1,1,2-TRICHLOROETHANE
<br />Under the proper conditions it can undergo hazardous
<br />reactions with aluminum oxide + heavy metals; dinitrogen
<br />tetraoxide; inhibitors; metals (e.g., magnesium; aluminum;
<br />potassium; potassium-sodium alloy); sodium hydroxide;
<br />N104; oxygen. When heated to decomposition it emits toxic
<br />fumes of C1. Used as a cleaning solvent, a chemical inter-
<br />mediate to produce vinylidene chloride, and as a propellant
<br />in aerosol cans. See also CHLORINATED HYDROCAR-
<br />BONS, ALIPHATIC. For further information see methyl
<br />chloroform, Vol. 2, No. 5 of DPIM Report.
<br />TIN000
<br /> HR: 3
<br />1,1,2-TRICHLOROETHANE
<br />CAS: 79-00-5
<br /> NIOSH: KJ 3150000
<br />Mf. C1H3C13
<br /> mw: 133.40
<br />PROP: Liquid; pleasant odor. Bp: 114°, fp: —35°, d: 1.4416
<br />20°/4°, vap press: 40 mm @ 35.2°.
<br />SYNS:
<br />ETHANE TRICHLORIDE
<br />NCI-004579
<br />RCRA WASTE NUMBER U227
<br />0-T
<br />1.I.2-TRICHLORETHANE
<br />B-TRICHLOROET'HANE
<br />1.2.2-TRICHLOROETHANE
<br />TROJCHLOROETAN(1.1.2) (POL-
<br />ISH)
<br />VINYL TRICHLORIDE
<br />TOXICITY DATA:
<br />skn-rbt 500 mg open MLD
<br />skn-rbt 810 mg/24H SEV
<br />eye-rbt 162 mg MLD
<br />skn-gpg 1440 mg/15M
<br />otr-mus:emb 25 mg/L
<br />cyt-gpg-skn 2880 lig/kg
<br />dnd-mam:lym 1 mmol/L
<br />orl-mus TDLo:532 mg/kg (14D
<br />male): REP
<br />orl-mus TDLo:76 g/kg/78W-I:
<br />CAR
<br />orl-mus TD :152 g/kg/78W-I:
<br />CAR
<br />on-rat LD50:580 mg/kg
<br />ihl-rat LCLo:500 ppm/8H
<br />orl-mus LD50:378 mg/kg
<br />ipr-mus LD50:494 mg/kg
<br />scu-mus LD50:227 mg/kg
<br />on-dog LDLo:500 mg/kg
<br />ipr-dog LD50:450 mg/kg
<br />ivn-dog LDLo:95 mg/kg
<br />ihl-cat LCLo:13100 mg/m3/4.5H
<br />skn-rbt LD50:3730 mg/kg
<br />scu-rbt LDLo:500 mg/kg
<br />IARC Cancer Review: Animal Limited Evidence IMEMDT
<br />20,533,79. NCI Carcinogenesis Bioassay (gavage); No Evi-
<br />dence: rat NCITR* NCI-CG-TR-74,78; (gavage); Clear
<br />Evidence: mouse NCITR* NCI-CG-TR-74,78. Community
<br />Right To Know List. Reported in EPA TSCA Inventory.
<br />OSHA PEL: TWA 10 ppm (skin)
<br />ACGIH TLV: TWA 10 ppm (skin)
<br />DFG MAK: 10 ppm (55 mg/m3)
<br />3328
<br />THR: Poison by ingestion, intravenous and subcutaneous
<br />routes. Moderately toxic by inhalation, skin contact, and
<br />intraperitoneal routes. An experimental carcinogen. Experi-
<br />mental reproductive effects. Mutagenic data. An eye and
<br />severe skin irritant. Has narcotic properties and acts as a
<br />local irritant to the eyes, nose and lungs. It may also be
<br />injurious to the liver and kidneys. Incompatible with potas-
<br />sium. When heated to decomposition it emits toxic fumes
<br />of Cl. A priority pollutant associated with EPA superfund
<br />sites. See also CHLORINATED HYDROCARBONS, AL-
<br />IPHATIC and other trichloroethane entries. For further in-
<br />formation, see Vol. 5, No. 3 of DPIM Report.
<br />TIN500
<br /> HR: 3
<br />TRICHLOROETHANOL
<br />CAS: 115-20-8
<br /> NIOSH: KM 3850000
<br />mf: C-,113C130 mw: 149.40
<br />PROP: Liquid. Mp: 17.8°, bp: 150° (Cy 765 mm, d: 1.54
<br />@25/4°, vap press: 1 mm @ 20°, vap d: 5.16.
<br />SYNS:
<br />TRICHLORETHANOL
<br />2.2.2-TRICHLOROETHANOL
<br />TRICIILOROETHYL ALCOHOL
<br />TOXICITY DATA:
<br />mmo-asn 5 µ1/plate/2H
<br />sln-asn 10240 µmon
<br />sce-hmn:lym 178 g/L
<br />on-rat LDLo:500 mg/kg
<br />ipr-rat LDLo:300 mg/kg
<br />orl-mus LDLo:500 mg/kg
<br />ivn-mus LD50: 201 mg/kg
<br />ivn-rbt LDLo:50 mg/kg
<br />rec-rbt LDLo:500 mg/kg
<br />EPA Genetic Toxicology Program. Reported in EPA TSCA
<br />Inventory.
<br />THR: Poison by intravenous and intraperitoneal routes.
<br />Moderately toxic by ingestion and rectal routes. Human
<br />mutagenic data. Explosive reaction with concentrated so-
<br />dium hydroxide solutions. When heated to decomposition
<br />it emits toxic fumes of CI — . Used as an hypnotic and anes-
<br />thetic. See also CHLORINATED HYDROCARBONS,
<br />ALIPHATIC.
<br />332c
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<br />CODEN:
<br />UCDS** 6/28/72
<br />JETOAS 9,171,76
<br />JETOAS 9,171,76
<br />APT0A6 41,298,77
<br />CALEDQ 28.85,85
<br />APT0A6 41,298,77
<br />TODED5 11,243,82
<br />DCTODJ 8,333,85
<br />NCITR* NCI-CG-TR-
<br />74,78
<br />NCITR* NCI-CG-TR-
<br />74.78
<br />AIHAAP 30,470,69
<br />AIHAAP 30,470,69
<br />DCTODJ 8,333.85
<br />TXAPA9 9,139.66
<br />JPETAB 123,224,58
<br />AJHYA2 16,325,32
<br />TXAPA9 10,119,67
<br />QJPPAL 7,205,34
<br />AHBAAM 116,131.36
<br />AIHAAP 30,470,69
<br />QJPPAL 7,205,34
<br />2.2.2-TRICHLOROETHYL ALCO-
<br />110L
<br />CODEN:
<br />CBINA8 30,9.80
<br />MUREAV 155.105,85
<br />TOERD9 3.63.81
<br />CRAA7 17.258,38
<br />JPETAB 63,453,38
<br />CRAAA7 17,258,38
<br />28ZPAK -.78,72
<br />JPETAB 63,453.38
<br />CRAA7 17,258,38
<br />TIN750
<br /> HR: 3
<br />TRICHLOROETHENYLSILANE
<br />CAS: 75-94-5 NIOSH: VV 6125000
<br />DOT: 1305
<br />C2H3C13S
<br /> mw: 161.49
<br />PROP: Fuming liquid. Bp: 90.6°, d: 1.265 (th 25/25°, flash
<br />p: 16°F.
<br />SYNS:
<br />SILANE, VINYL TRICHLORO 1-150 VINYLSILICON TRICHLORIDE
<br />TRICHLORO(VINYL)SILANE
<br /> VINYL TRICHLOROSILANE (DOT)
<br />TRICHLOROVINYL SILICANE
<br /> VINYL TRICHLOROSILANE. IN-
<br />UNION CARBIDE A-I50
<br /> HIBITED (DOT)
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