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Geophysical investigation of glass ‘hotspots’ in glass dumps as potential <br />secondary raw material sources <br />Richard Nasilele Mutafela <br />a,⇑, Etzar Gomez Lopez <br />b, Torleif Dahlin <br />b, Fabio Kaczala <br />c, Marcia Marques <br />a,d, <br />Yahya Jani <br />a, William Hogland <br />a <br />a Department of Biology & Environmental Science, Faculty of Health and Life Sciences, Linnaeus University, SE-391 82 Kalmar, Sweden <br />b Division of Engineering Geology, Lund University, P.O. Box 118, SE-221 00 Lund, Sweden <br />c Sweco Environment AB, SE-392 35 Kalmar, Sweden <br />d Department of Sanitary and Environmental Engineering, Rio de Janeiro State University UERJ, R. São Francisco Xavier, 524, CEP 20551-013, Rio de Janeiro, Brazil <br />article info <br />Article history: <br />Received 8 July 2019 <br />Revised 31 January 2020 <br />Accepted 18 March 2020 <br />Keywords: <br />Electrical resistivity tomography <br />Secondary resources <br />Glass waste <br />Landfill mining <br />Waste characterisation <br />Circular economy <br />abstract <br />This study investigates the potential for Electrical Resistivity Tomography (ERT) to detect buried glass <br />‘hotspots’ in a glass waste dump based on results from an open glass dump investigated initially. This <br />detection potential is vital for excavation and later use of buried materials as secondary resources. <br />After ERT, test pits (TPs) were excavated around suspected glass hotspots and physico-chemical charac- <br />terisation of the materials was done. Hotspots were successfully identified as regions of high resistivity <br />(>8000 Xm) and were thus confirmed by TPs which indicated mean glass composition of 87.2% among <br />samples (up to 99% in some). However, high discrepancies in material resistivities increased the risk <br />for introduction of artefacts, thus increasing the degree of uncertainty with depth, whereas similarities <br />in resistivity between granite bedrock and crystal glass presented data misinterpretation risks. <br />Nevertheless, suitable survey design, careful field procedures and caution exercised by basing data inter- <br />pretations primarily on TP excavation observations generated good results particularly for near-surface <br />materials, which is useful since glass waste dumps are inherently shallow. Thus, ERT could be a useful <br />technique for obtaining more homogeneous excavated glass and other materials for use as secondary <br />resources in metal extraction and other waste recycling techniques while eliminating complicated and <br />often costly waste sorting needs. <br />2020 The Authors. Published by Elsevier Ltd. ThisisanopenaccessarticleundertheCCBY-NC-NDlicense <br />(http://creativecommons.org/licenses/by-nc-nd/4.0/). <br />1. Introduction <br />The world population has been increasing together with <br />resource consumption and waste generation, resulting in negative <br />environmental impacts. It is projected to further increase to 9.8 bil- <br />lion by 2050, which is expected to triple the current resource <br />demand to 140 billion tonnes of minerals, ores, fossil fuels and bio- <br />mass per year (UN, 2017; UNEP, 2011). Decoupling of the economic <br />growth rate from this high rate of natural resource consumption is <br />thus recommended. In case of metals production, decrease in ore <br />grades and stocks have been reported due to the need to meet <br />the global demand (UNEP, 2013). Some trace elements such as <br />Sb, As, Cd and Pb have been identified as high supply risk due to <br />their low recycling rates, limited number of substitutes and being <br />almost exclusively mined as by-product metals (British Geological <br />Survey, 2015). The growing calls for secondary raw materials and <br />reduced mining will further drop the supply of such elements. <br />Therefore, alternative and sustainable sources are required. <br />Around former glass factories in south-eastern Sweden, glass <br />dumps are highly contaminated with As, Cd, Pb and Sb, with an <br />estimation of 420,000 m <br />3 of contaminated materials (420 tonnes <br />of As, 30 tons of Cd and 3100 tons of Pb) in 22 dumps (Höglund <br />et al., 2007). These materials pose contamination risks to humans <br />and the environment (Augustsson et al., 2016), hence they have <br />been recommended for remediation (Hogland et al., 2010). Alster- <br />fors glass waste dump (current study site), for example, has an <br />infiltration rate to groundwater of about 1200 m <br />3 per year and <br />combined As, B, Cd, Pb and Sb leakages to the Alsterån River at <br />more than 20 kg per year (Höglund et al., 2007). These materials, <br />on the other hand, could potentially contribute as secondary <br />sources of some of the high supply risk metals. High contamination <br />of excavated wastes is one of the main obstacles to their recycling <br />as secondary raw materials (Hull et al., 2005), resulting in <br />https://doi.org/10.1016/j.wasman.2020.03.027 <br />0956-053X/2020 The Authors. Published by Elsevier Ltd. <br />This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). <br />⇑Corresponding author at: Department of Biology & Environmental Science, <br />Faculty of Health and Life Sciences, Linnaeus University, Stuvaregatan 2, SE-392 31 <br />Kalmar, Sweden. <br />E-mail address:richardnasilele.mutafela@lnu.se (R.N. Mutafela). <br />Waste Management 106 (2020) 213–225 <br />Contents lists available at ScienceDirect <br />Waste Management <br />journal homepage: www.elsevier.com/locate/wasman