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Mr. Roger Smith - 2 - 9 September 2021 <br /> The 2005 Revised Groundwater Cleanup and Contingency Plan and the 22 February <br /> 2006 Central Valley Water Board letter (collectively, the Cleanup Plan) established <br /> groundwater cleanup levels, threshold concentrations for the protection of human health <br /> for the vapor intrusion pathway, and performance criteria for the current remedy to <br /> monitor its effectiveness. <br /> Because regulatory vapor intrusion screening levels have been revised/updated over <br /> the years and VOCs are present in groundwater near and beneath a portion of the <br /> residential area at concentrations that exceed the current San Francisco Bay Regional <br /> Water Quality Control Board Environmental Screening Levels (ESLs) for vapor <br /> intrusion, Central Valley Water Board staff requested that the most up-to-date vapor <br /> intrusion screening levels be used to evaluate whether the current phytoremediation <br /> and MNA remedy is protective of human health. <br /> VOCs detected in groundwater beneath the Site include 1 ,2-dichloropropane (1,2-DCP), <br /> 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (DBCP), and <br /> chloroform. During the most recent groundwater monitoring event (February 2021), <br /> 1,2-DCP and chloroform were detected at concentrations that exceeded their respective <br /> ESLs for vapor intrusion. <br /> REVIEW OF WORK PLAN <br /> Geosyntec proposes to collect soil vapor samples at two on-Site locations, near <br /> monitoring wells MW-5B and MW-713. The highest concentrations of 1,2-DCP and <br /> 1,2,3-TCP were detected at these wells during the most recent monitoring event. Soil <br /> vapor probes will be installed approximately 10 feet and 15 feet east of MW-513 and <br /> MW-713, respectively. <br /> The proposed soil vapor probes will be installed at depths of approximately 5 and 10 <br /> feet below ground surface at each location. Borings for the soil vapor probes will be <br /> advanced using direct push technology. Soil cores will be collected during drilling and <br /> will be visually logged and screened for the presence of VOCs using a hand-held <br /> photoionization detector. Soil samples will also be collected for analysis of physical <br /> properties. <br /> The soil vapor probes will be constructed using a 1/2-inch diameter, 6-inch-long <br /> stainless-steel screen attached to 1/4-inch diameter Nylaflow®tubing. The probes will <br /> be installed and sampled in accordance with the Department of Toxic Substances <br /> Control July 2015 Advisory - Active Soil Gas Investigations. Soil vapor sampling will be <br /> conducted a minimum of 48 hours following installation of the vapor probes. Prior to <br /> collecting soil vapor samples, shut-in testing, leak testing (using a shroud and helium as <br /> the tracer gas), and purging will be conducted. Soil gas samples will be collected using <br /> laboratory supplied 1-liter SUMMA canisters. Collected soil gas samples will be <br /> submitted to a State-of-California certified analytical laboratory under chain-of-custody <br /> procedures for analyses of VOCs using EPA Method TO-15 and helium by ASTM <br /> International D-1946. <br />