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stale of California <br /> Memorandum <br /> To Ray Menebroker, Manager Date January 11, 1984 <br /> SourceEvaluation Section Subject Sampling at Forward, Inc. <br /> Class II-1 Landfill in <br /> Stockton <br /> Janette Munson, Source Evaluation Section <br /> Rich Vincent, Technology Assessment Section / .? <br /> Stationary Source Division <br /> From Air Resources Board <br /> In August 1983, while working in the Enforcement (now Compliance) Division, <br /> we collected samples of ambient air in and around Forward, Inc. Class <br /> II-1 landfill in Stockton. We also sampled for emissions from the landfill <br /> surface. The attached memo dated August 11 , 1983, describes the samples, <br /> their locations, the sampling method used, and the requested analyses. <br /> Attachment II shows the wastes reportedly buried at the fill . Attachment <br /> III shows the laboratory results. <br /> The sampling was part of EnforcementDivision's project of characterizing <br /> emissions from class II-1 and class I landfills. Forward was chosen because <br /> it was then a center of controversy regarding alleged groundwater pollution <br /> affecting the farm land surrounding the fill . Enforcement Division had <br /> urged the San Joaquin County APC, to test at Forward. The APCD declined <br /> but by a letter on June 28, 1983, invited the ARB to test. <br /> The "CSI" samples were withdrawn from under buckets inverted over the <br /> trenches. They were intended for comprehensive analyses for hydrocarbons <br /> and chlorinated hydrocarbons (the Tenax samples) and for pesticides (the <br /> XAD samples). The results of those analyses were used to determine the <br /> amount and type of analytical work needed on the much more numerous ambient <br /> air ("AMB") samples. <br /> GC/MS analyses of the CSI samples on Tenax (AIHL Lab. No. 31601 ) indicated <br /> negligible amounts of compounds of concern except toluene and chloroform. <br /> These compounds were also present as contaminants in the blank for the <br /> CSI Tenax samples, so the compounds cannot be regarded as emissions from <br /> the fill . <br /> The pond water samples (AIHL Lab No. 31603) were analyzed for organic <br /> gases in their equilibrium vapor spaces. No organic compounds were detected <br /> above 0.10 ppm(v) <br /> In view of the lack of indication that either the ponds or the trenches <br /> wore emitting anything, only a few of the ambient air samples on carbon <br /> were analyzed (AIHL Lab No. 31604) . Two samples at site 4 indicated no <br /> chlorinated compounds significantly above concentrations present in their <br /> associated blank (which was contaminated with methylene chloride (CH C1 ) , <br /> chloroform (CHC13) , and perchloroethylene (C204)) . Three samples Meh at <br /> site 2 showed no detectable (less than 0.1 mg of) benzene, toluene, or <br /> Xylene and no detectable (less than .01 mg of) styrene. All calculated <br /> concentrations (uncorrected by blank analyses) of carbon sample analates <br /> in air are at least two orders of magnitude below NIOSH/OSHA workplace <br /> standards. <br />