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Skin l In case of contact, immediately flush with plenty of water for at least 15 minutes. Take <br />off contaminated clothing. If irritation develops and persists, get medical attention. <br />Eye l IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, <br />if present and easy to do. Continue rinsing. If eye irritation persists: Get medical <br />advice/attention. <br />Ingestion l Ingestion is not considered a potential route of exposure. <br />4.2 Most important symptoms and effects, both acute and delayed <br />l Refer to Section 11 - Toxicological Information. <br />4.3 Indication of any immediate medical attention and special treatment needed <br />Notes to Physician l Treat symptoms and eliminate over-exposure. Hyperbaric oxygen is the most efficient <br />antidote to Carbon Monoxide poisoning, the optimum range being 2-2.5 atm. A special <br />mask, or, preferably, a compression chamber to utilize oxygen at these pressures is <br />required. Avoid administering stimulant drugs. Be observant for initial signs of <br />pulmonary edema in the event of severe inhalation over-exposures. <br />4.4 Other information <br />l RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO <br />THIS GAS MIXTURE WITHOUT ADEQUATE PERSONAL PROTECTIVE <br />EQUIPMENT. At a minimum, Self-Contained Breathing Apparatus must be worn. <br />Victim(s) who experience any adverse effect after over-exposure to this gas mixture <br />must be taken for medical attention. Rescuers should be taken for medical attention if <br />necessary. Take a copy of the label and the MSDS to physician or other health <br />professional with victim(s). <br />Section 5 - Firefighting Measures <br />5.1 Extinguishing media <br />Suitable Extinguishing Media l Non-flammable gas mixture. Use extinguishing media appropriate for surrounding fire. <br />Unsuitable Extinguishing <br />Media <br />l No data available <br />5.2 Special hazards arising from the substance or mixture <br />Unusual Fire and Explosion <br />Hazards <br />l This gas mixture contains toxic gases, Hydrogen Sulfide and Carbon Monoxide, and <br />presents a health hazard to firefighters. This gas mixture is not flammable; however, <br />containers, when involved in fire, may rupture or burst in the heat of the fire. <br />Hazardous Combustion <br />Products <br />l No data available <br />5.3 Advice for firefighters <br />l Structural firefighters' protective clothing will only provide limited protection. <br />Wear positive pressure self-contained breathing apparatus (SCBA). <br />Section 6 - Accidental Release Measures <br />6.1 Personal precautions, protective equipment and emergency procedures <br />Personal Precautions l Wear appropriate personal protective equipment. See section 8 for more information. <br />Emergency Procedures l Due to the small size and content of the cylinder, an accidental release of this gas <br />mixture presents significantly less risk of over-exposure to Hydrogen Sulfide and <br />Carbon Monoxide, the toxic components of this gas mixture, and other safety hazards <br />related to the remaining components of this gas mixture, than a similar release from a <br />larger cylinder. In the event of a release in which the atmosphere is unknown, and in <br />which other chemicals are potentially involved, evacuate immediate area. Such <br />releases should be responded to by trained personnel using pre-planned procedures. <br />Proper protective equipment should be used. In case of a leak, clear the affected area, <br />protect people, and respond with trained personnel. <br />0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance <br />Preparation Date: 10/August/2012Preparation Date: 10/August/2012Preparation Date: 10/August/2012Preparation Date: 10/August/2012 <br />Revision Date: 16/December/2013Revision Date: 16/December/2013Revision Date: 16/December/2013Revision Date: 16/December/2013 <br />Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) <br />OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/DPDDPDDPDDPDPage 5 of 18Page 5 of 18Page 5 of 18Page 5 of 18