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6.2 Environmental precautions <br />l Avoid release to the environment. <br />6.3 Methods and material for containment and cleaning up <br />Containment/Clean-up <br />Measures <br />l Allow the gas mixture to dissipate. <br />If necessary, monitor the surrounding area (and the original area of the release) for <br />concentrations of component gases. <br />Concentrations of component gases must be below any exposure limits listed in <br />Section 8 and Oxygen levels must be above 19.5% before non-emergency personnel <br />are allowed to re-enter area. <br />6.4 Reference to other sections <br />l Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal <br />Considerations. <br />Section 7 - Handling and Storage <br />7.1 Precautions for safe handling <br />Handling l Use good safety and industrial hygiene practices. Use only with adequate ventilation. <br />Be aware of any signs of dizziness or fatigue, especially if work is done in a poorly <br />ventilated area; exposures to fatal concentrations of this gas mixture could occur <br />without any significant warning symptoms, due to olfactory fatigue or oxygen <br />deficiency. Cylinders should be firmly secured to prevent falling or being knocked-over. <br />Do not attempt to repair, adjust, or in any other way modify cylinders. If there is a <br />malfunction or another type of operational problem, contact nearest distributor <br />immediately. <br />7.2 Conditions for safe storage, including any incompatibilities <br />Storage l Cylinders should be stored in dry, well-ventilated areas away from sources of heat, <br />ignition and direct sunlight. Do not allow area where cylinders are stored to exceed <br />52°C (125°F). Cylinders must be protected from the environment, and preferably kept <br />at room temperature (approximately 21°C (70°F). Cylinders should be firmly secured <br />to prevent falling or being knocked-over. Protect cylinders against physical damage. <br />Store locked up. <br />7.3 Specific end use(s) <br />l Refer to Section 1.2 - Relevant identified uses. <br />Section 8 - Exposure Controls/Personal Protection <br />8.1 Control parameters <br />Exposure Limits/Guidelines <br /> Result ACGIH Canada Ontario Canada Quebec China Germany DFG <br />Carbon monoxide <br />(630-08-0) <br />Ceilings Not established Not established Not established <br />20 mg/m3 MAC (high <br />altitude area, 2000- <br />3000m); 15 mg/m3 <br />MAC (high altitude <br />area, >3000m) <br />30 ppm Peak; 35 <br />mg/m3 Peak <br />STELs Not established 100 ppm STEV; 115 <br />mg/m3 STEV <br />200 ppm STEV; 230 <br />mg/m3 STEV <br />30 mg/m3 STEL (not <br />in high altitude area)Not established <br />TWAs 25 ppm TWA 25 ppm TWAEV; 29 <br />mg/m3 TWAEV <br />35 ppm TWAEV; 40 <br />mg/m3 TWAEV <br />20 mg/m3 TWA (not <br />in high altitude area)Not established <br />MAKs Not established Not established Not established Not established 30 ppm MAK; 35 <br />mg/m3 MAK <br />Methane <br />(74-82-8)TWAs 1000 ppm TWA 1000 ppm TWAEV Not established Not established Not established <br />0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance0.0015 – 23.5% Oxygen; 0.0005% – 2.5% Methane; 0.0005 – 1.0% Carbon Monoxide; 0.001 – 0.025% Hydrogen Sulfide; Nitrogen Gas balance <br />Preparation Date: 10/August/2012Preparation Date: 10/August/2012Preparation Date: 10/August/2012Preparation Date: 10/August/2012 <br />Revision Date: 16/December/2013Revision Date: 16/December/2013Revision Date: 16/December/2013Revision Date: 16/December/2013 <br />Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US)Format: EU CLP/REACH Language: English (US) <br />OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/OSHA HCS 1994, WHMIS, UN GHS, EU CLP, EU DSD/DPDDPDDPDDPDPage 6 of 18Page 6 of 18Page 6 of 18Page 6 of 18