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Vapor Intrusion Assessment Work Plan Project number:60653972 <br /> milligrams per cubic meter(mg/m3)for 1,1-DCE in four samples, 0.92 mg/m3 TCE in one sample,and <br /> less than 0.03 and 0.38 mg/m3 for PCE and toluene,respectively.After achieving low and asymptotic <br /> concentrations of VOCs in the four vapor extraction wells and the confirmation soil vapor sampling, soil <br /> closure was achieved in 2001 for no further soil action(Parsons 2001), and the SVE treatment system was <br /> disassembled in December 2001. <br /> Because GWETS VOC mass removal resulted in decreasing the mass from over 20 pounds per year in <br /> 2000 to 0.8 pounds per year in 2015 (Parsons 2016a),Parsons submitted a Proposal for MNA Study at <br /> Applied Aerospace Structures Corporation Stockton, California recommending that a MNA/rebound <br /> study be conducted(Parsons 2013). On January 8,2014, CVRWQCB responded and indicated that <br /> TCE remained above WQOs in the source area and requested to conduct pumping rate <br /> optimization to determine whether the VOC recovery could be enhanced by decreasing the pump rate. If <br /> enhanced TCE removal could not be achieved by decreasing the pump rate, CVRWQCB would consider <br /> the MNA study proposal.In 2016,Parsons submitted the Optimization for Groundwater Pumping,which <br /> concluded that VOC recovery could not be enhanced by decreasing pumping rates(Parson 2016b). <br /> In May 2016, an In Situ Chemical Oxidation(ISCO)Work Plan(AECOM Technical Services,Inc. <br /> [AECOM] 2016a)using sodium persulfate catalyzed by iron-ethylenediaminetetraacetic acid(Fe-EDTA) <br /> was submitted for CVRWQCB's review to treat the residual groundwater VOCs in the source or <br /> remaining areas with relatively high concentrations. The purpose of ISCO treatment was to accelerate the <br /> reduction of the residual groundwater VOC mass prior to transit to naturally occurring processes to <br /> attenuate any remaining groundwater VOC contamination.AECOM received CVRWQCB's review <br /> comments on the ISCO Work Plan in February 2017 and submitted responses on November 3,2017. <br /> With CVRWQCB's approval,the GWETS operation was suspended on December 20, 2016,to allow the <br /> groundwater level to recover in preparation for ISCO injection. The scope of work for the groundwater <br /> monitoring event in July 2017 was modified to address several of CVRWQCB's review comments on the <br /> ISCO Work Plan.This additional sampling included the collection of baseline metals and total dissolved <br /> solids samples to ensure compliance with the requirements of the Waste Discharge Requirements Permit <br /> under the General Order for In-Situ Groundwater Remediation And Discharge of Treated Groundwater to <br /> Land(CVRWQCB Order No.R5-2015-0012). The baseline evaluation results,and proposed path forward <br /> were submitted as part ofAECOM's response to CVRWQCB's ISCO Work Plan comments on <br /> November 3,2017. <br /> Due to the observation of consistent VOC concentrations detected and the lack of plume migration based <br /> on the July 2017 sampling results(AECOM 2017), CVRWQCB agreed to keep the GWETS offline while <br /> collecting more post-GWETS data in order to evaluate another remedial alternative. For example, a <br /> round of MNA parameter sampling was performed in August 2018 to assess whether MNA was ongoing, <br /> while multiple rounds of Site-wide VOC sampling were performed to confirm the stabilized concentration <br /> trends.Based on the review of the post-GWETS data, CVRWQCB recommended during a January 10, <br /> 2019 conference call with AECOM that a Proposed Remedial Alternative Work Plan,which may include <br /> MNA and a contingency plan,be submitted to replace the current ineffective GWETS in order to continue <br /> Site remediation. Subsequently,AECOM submitted the Proposed Remedial Alternative Work Plan(dated <br /> March 15, 2019)for the continuation of Site remediation. CVRWQCB provided review comments on the <br /> Proposed Remedial Alternative Work Plan on July 1,2019, and AECOM submitted the Revised Proposed <br /> Remedial Alternative Work Plan(AECOM 2019a)to incorporate CVRWQCB's review comments. <br /> Subsequently, CVRWQCB issued MRP No.R5-2019-0906(dated November 6,2019)to request MNA to <br /> start during the 3rd Quarter 2019. <br /> In the Annual Monitored Natural Attenuation Report 4th Quarter 2021 —3rd Quarter 2022 prepared by <br /> AECOM groundwater sampling results indicated generally stable VOC concentrations in sampled wells, <br /> with only small concentration increases in MW-13,MW-17,and GW-2R(AECOM, 2022).Upon review <br /> of the report, CVRWQCB indicated further soil gas investigation up to the current regulatory standard <br /> Prepared for: California Regional Water Quality Control Board,Central Valley Region AECOM <br />