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Mr. Jason Gaitan <br /> July 13, 2020 <br /> at the active industrial rail yard Site. The C/I ESLs for TPH-DRO and TPH-MO are 1,200 milligrams per <br /> kilogram (mg/kg) and 180,000 mg/kg, respectively (SF-RWQCB 2019). <br /> Data Validation <br /> Pace laboratory analytical reports were validated by GHD Inc. (GHD) in a memoranda dated July 9, 2020. <br /> Based on the GHD assessment in the data validation memorandum, the data associated with this project <br /> is acceptable without qualification. Samples were prepared and analyzed within the required holding <br /> times. Analytical results and data validation are included in Attachment 2. <br /> Soil Analytical Chromatogram Review <br /> Laboratory chromatograms for the TPH-DRO data were compared against the TPH-DRO standard <br /> chromatograms to assess the type of petroleum hydrocarbon present and the degree of weathering for <br /> the TPH-DRO concentrations in the soil samples. The purpose of the chromatogram review was to <br /> identify the soil samples with non-weathered diesel detections to be removed during the excavation <br /> proposed in this Work Plan. <br /> Signatures of non-weathered diesel to severely weathered diesel and oil mixtures, or natural organic <br /> matter were observed in the chromatograms. Non-weathered diesel was noted in samples SS-1-16, SS- <br /> 1-22, SS-1-48, SS-4-12, SS-4-40, SS-5-14, SS-6-14, SS-7-17, and SS-7-60. Diesel appeared slightly <br /> more weathered in lighter-range hydrocarbons compared to the shallower samples in samples SS-1-48, <br /> SS-4-40, and SS-7-60. This is likely due to evaporation during migration from shallower sediments. <br /> Severely weathered diesel was present in samples SS-2-16, SS-3-14, SS-5-49, and SS-6-46. TPH-DRO <br /> was not detected above the laboratory reporting limit(RL) in samples SS-2-54, SS-3-14, SS-5-49, SS-8- <br /> 9, SS-8-24, SS-9-22, and SS-9-33. Copies of the chromatograms are included in Attachment 2. <br /> Soil Analytical Results and Evaluation <br /> TPH-DRO concentrations in soil samples ranged from not detected above the RL to 9,100 milligrams per <br /> kilogram (mg/kg; SS-1-22). TPH-DRO concentrations exceeded the 1,200 mg/kg C/I ESL in six shallow <br /> soil samples SS-1-16, SS-1-22, SS-4-12, SS-5-14, SS-6-14, and SS-7-17.Analytical results indicate that <br /> TPH-DRO is generally delineated laterally in soil borings to the east by SS-2 and SS-3, to the southwest <br /> by SS-8, and to the northwest by SS-9. TPH-DRO is delineated vertically at each sample location. <br /> TPH-MO concentrations in soil samples ranged from not detected above the RL to 1,060 mg/kg (SS-5- <br /> 14). TPH-MO concentrations did not exceed the 180,000 mg/kg C/I ESL. <br /> Soil analytical results are presented in Table 1 and on Figure 3. Laboratory analytical reports, <br /> chromatograms, and chain-of-custody documentation are included in Attachment 2. <br /> PROPOSED SCOPE OF WORK <br /> An additional excavation is proposed to remove remaining diesel-impacted soil above the C/I ESL <br /> associated to the November 10, 2019 release area. The proposed excavation area is shown on Figure 3 <br /> and generally delineated by areas of severely weathered diesel and where TPH-DRO concentrations in <br /> soil samples were below the C/I ESL. <br /> arcadis.com Page: <br /> 2020.07.13_Soil Sample Summary and Excavation Work Plan.docx <br /> 3/5 <br />