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January 17,2023 <br /> Rania Zabaneh <br /> Page 2 of 4 <br /> Reference:Transmittal of Supplemental Site Investigation Work Plan and Response to Comments-South Pointe <br /> Property-701, 705,833,&855 West Weber Avenue,Stockton,California <br /> Other SLs include screening levels that may be appropriate for some chemicals and/or some <br /> media are the Environmental Screening Levels (ESLs) published by San Francisco Bay Regional <br /> Water Quality Control Board (see example in item #3 below). <br /> Stantec response: Tables included in Appendix D of the Work Plan include selected screening <br /> levels for analytes. <br /> Comment #3 -Screening levels for petroleum hydrocarbon mixtures reported as TPH: DTSC often <br /> uses the ESLs for the evaluation of petroleum data reported as gasoline, diesel and/or motor oil <br /> range TPH. If you plan on having your petroleum results reported as "TPH", please make sure that <br /> the samples for petroleum hydrocarbon mixtures are not treated with silica gel cleanup. Silica gel <br /> cleanup (SGC) is not part of a normal sample prep for petroleum hydrocarbon analysis. Most of <br /> the petroleum present in water is in the form of hydrocarbon oxidation products (HOPS) and SGC <br /> removes the HOPS. Petroleum hydrocarbons themselves are not very soluble, especially the larger <br /> ones. Also, there is no SGC-step in the TPH method (USEPA method 80156). Detailed explanations <br /> of analysis methods and screening levels for petroleum mixtures can be found in the ESLs User's <br /> Guide, in the ITRC TPH Risk guidance and in DTSC's HHRA Note 12. In this context I would like to <br /> note that on page 3 of the Supplemental Work Plan under "Further Assessment of groundwater <br /> conditions is not necessary ..." the second paragraph starts with "Low concentrations of motor oil <br /> in groundwater ...". Since motor oil-range hydrocarbons are not soluble in water, this statement <br /> raises questions. Therefore, collecting current groundwater (GW) water samples and making sure <br /> they are properly analyzed may help to better understand the level of GW contamination. <br /> Stantec response: Grab groundwater samples will be analyzed for total petroleum hydrocarbons <br /> (TPH) as gasoline, diesel, and motor oil, and results compared to ESLs established by the San <br /> Francisco Bay RWQCB. <br /> Comments from Peter Cooke, DTSC geologist. <br /> Comment #1 - Polychlorinated biphenyls (PCBs) were detected at sampling location PL-9 at 3' <br /> bgs (66 mg/kg). This location should be further characterized during the upcoming Supplemental <br /> Work Plan field work. <br /> Stantec response: Boreholes 27a, 27b, and 27c have been added to further investigate historical <br /> detections of PCBs at location PL-9. <br /> Comment #2 - Pentachlorophenol has been released from the adjacent McCormick & Baxter <br /> Superfund site. It should be determined if the soil of the South Pointe property could have been <br /> impacted. If so, the analysis of the proposed soil samples should include pentachlorophenol. <br /> Stantec response: The McCormick & Baxter creosoting site is located at 1214 Washington Street <br /> West, across Interstate 5 and approximately 2,000 feet southwest of the project site. Based on this <br /> distance, it seems unlikely that airborne contaminants such as pentachlorophenol would have <br /> reached the site at appreciable concentrations. Soil samples from ground surface and 4 feet <br /> Design with community in mind <br />