Laserfiche WebLink
A=COM <br /> 4.19.1 Neutralization refers to the on-site neutralization of the cylinder contents through a controlled <br /> chemical reaction process. Specialized equipment may be necessary based on the chemical <br /> involved, as well as reaction by-products, catalysts, or physical conditions(i.e.,temperature, acidic, <br /> basic, etc.). Neutralization activities will be performed in accordance with the following procedures: <br /> • Neutralization is the required disposition method for cylinders containing acid gases, as well as <br /> many alkaline gases. <br /> • The neutralization process shall be approved by a professional engineer(e.g., chemical)or <br /> based on a published chemical-specific neutralization methodology. <br /> • Liquid levels in the reaction vessels will be maintained at least 12 inches (30.5 centimeters) <br /> below the top of the vessel. <br /> • Based on the specific chemical reaction, the temperature of the reaction vessel and its <br /> contents will be monitored continuously and controlled accordingly. <br /> • Pressure levels will be maintained within acceptable limits to prevent the reaction from <br /> accelerating, unwanted by-product formation, or the break-through of the chemical intended to <br /> be neutralized. <br /> • Employees involved in neutralization activities shall be appropriately trained and wear the PPE <br /> identified within the site-specific safety plan and cylinder plan. <br /> 4.20 Detonation <br /> 4.20.1 Detonation refers to the use of explosives to open and subsequently consume the contents of the <br /> cylinder by the heat generated during the explosion. Detonation activities will be performed in <br /> accordance with the following procedures: <br /> • All personnel involved with detonation activities shall be appropriately trained and wear PPE <br /> appropriate to the hazards(e.g. Nomex fire-retardant forearm-length gloves, other fire- <br /> retardant clothing, self-contained breathing apparatus, etc.). <br /> • A detonation plan shall be submitted to and approved by the SH&E Manager prior to the <br /> commencement of cylinder detonation activities. <br /> • The detonation of compressed gas cylinders will be completed under the guidance of <br /> experienced ordnance and explosives (OE)professional who is licensed in the use of <br /> explosives. <br /> • A sufficient amount of explosives will be used to consume the entire contents of the cylinder <br /> (flammable gases only). <br /> • A blast pit will be excavated where all detonations will take place. <br /> • The OE professional will determine the blast hazard zone/potential debris impact zone, and <br /> this area will be evacuated prior to the detonation. <br /> • The OE professional will sound a warning signal (e.g., horn or equivalent)three times to <br /> indicate that a detonation is imminent and confirm all persons have evacuated the blast hazard <br /> zone prior to detonation. <br /> • Employees will be on standby outside the blast hazard zone with fire extinguishers(minimum <br /> rating of 20A:100B:C). <br /> 4.21 Cylinder Decommissioning Operations <br /> 4.21.1 Decommissioning refers to the removal of a compressed gas cylinder from service by rendering it <br /> permanently unusable. <br /> 4.21.2 Prior to decommissioning, cylinder contents will be verified, removed from the cylinder, and the <br /> cylinder purged with an inert gas(e.g., nitrogen, carbon dioxide, etc.). <br /> 4.21.3 All identifying marks or decals will be removed from the cylinder. <br /> Compressed Gases(S3AM-114-PR1) <br /> Revision 3 September 30,2020 <br /> PRINTED COPIES ARE UNCONTROLLED. CONTROLLED COPY IS AVAILABLE ON COMPANY INTRANET. 11 of 12 <br />