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M CDIM Standard Operating Procedure <br /> 4.1 Soil Vapor Sampling <br /> '"°'"""'"' Rev.1 6/30/2022 <br /> CDIM Standard Operating Procedure 4.1 <br /> Soil Vapor Sampling <br /> 1 PURPOSE <br /> This Standard Operating Procedure (SOP) establishes guidelines and procedures for <br /> collecting vapor samples from the subsurface. Several methods may be used to collect <br /> subsurface samples from boreholes; the more common drilling methods and sampling <br /> procedures are described below. Proper collection procedures are necessary to assure the <br /> quality of all subsurface vapor samples. Additional specific procedures and requirements will be <br /> provided in the project work plans, as necessary. <br /> Sampling of subsurface vapor is generally conducted to: <br /> 1. Evaluate whether releases of hazardous substances have occurred from <br /> underground or surface sources which may impact indoor air, outdoor air and <br /> groundwater. <br /> 2. Determine the extent of a hazardous release. <br /> 3. Design and monitor the performance of a soil vapor extraction system. <br /> 4. Map soil vapor plumes to select buildings for indoor air monitoring. <br /> 5. Provide confirmation subsurface vapor data following remediation. <br /> 2 DEFINITIONS <br /> 2.1 Borehole <br /> Any hole drilled into the subsurface for the purpose of identifying lithology, collecting soil, <br /> water, or vapor samples, and/or installing monitoring wells. <br /> 2.2 Subsurface Vapor Volatile Organic Compounds (VOCs) <br /> Subsurface vapors are chemicals that are emitted from certain subsurface solids or <br /> liquids and include a variety of chemicals. Samples that will be analyzed should be collected and <br /> contained in a manner that minimizes dilution or contamination of the sample, which could result <br /> in inaccurate results. Volatile organic compounds (VOCs) in subsurface vapors are typically <br /> analyzed using United States Environmental Protection Agency (USEPA) Method TO-15 for <br /> samples collected using Summa canisters. <br /> 2.3 Shroud <br /> An enclosure that is placed over all soil vapor sampling equipment, including the <br /> sampling container and the soil gas well annulus. In the interest of this SOP, a tracer gas (helium) <br /> is pumped into the shroud for the leak test prior to sample collection and during soil vapor sample <br /> collection. <br />