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OUTLINE FOR OXYGEN DIFFUSER TREATMENT <br />Treatment Description: <br />The treatment is the application of a patented method developed at the University of <br />Waterloo that uses oxygen diffusion to increase biological activity and the biodegradation <br />of BTEX and MtBE in groundwater. It works as an in -well remediation system that forms <br />an oxygen diffusion hallo around the treatment well. Details of the oxygen diffuser are <br />presented in the patent attached to this outline. The system uses sealed low density <br />polyethylene (LDPE) tubing charged with 60 pounds per square inch (psi) of oxygen to <br />diffuse oxygen into the treatment well at an equilibrium concentration of approximately <br />30 milligrams per liter (mg/L or ppm). SECOR will alter the design to increase oxygen <br />dispersion around the well by placing an in -well low -flow pump at the bottom of the <br />well. Water pumped from the bottom of the well, travels up the tubing placed in the well <br />to the screened interval at the groundwater surface where it mounds and increases water <br />flow out of the well into the surrounding sediments. The radius influence of the <br />treatment is assumed to be 1.5 times the distance between the inlet and outlet point. <br />Assuming a the pump is placed ten feet below the groundwater surface, the treatment <br />radius can be approximately 10 to fifteen feet depending on the permeability. Based on <br />evaluation of sediments in boring logs from the Site, the heterogeneity of sediments will <br />likely limit the zone of influence to under 15 feet. In addition, the presence of elevated <br />concentrations of BTEX has been shown in benchscale studies to decrease the efficiency <br />of MtBE biodegradation. The most effective treatment of MtBE has been demonstrated <br />in the field by researchers at the University of Waterloo. The researchers demonstrated <br />that MtBE can be degraded under high oxygen conditions (>20 ppm) in a 2 mile long <br />plume composed only of MtBE. The detailed description of the study is presented in the <br />papers attached to this document. <br />Proposed Treatment: <br />6 to 8 - 4" treatment wells spaced downgradient dispenser island from outside the <br />western edge of the former tank cavity to the eastern edge of the cavity forming <br />an oxygen permeable barrier to MtBE transport. Ideal spacing would be under <br />10 feet, to maintain high oxygen concentrations in the treatment area, <br />significantly increasing the effectiveness of MTBE degradation, but generating a <br />treatment system that would be cost prohibitive. <br />2 to 4 — 4" treatment wells within the tank cavity area to increase treatment in the source <br />area. <br />Wells will be treated with an oxygen diffusion device amended with an in -well pump. <br />Well monitoring, oxygen canister replacement, pump O & M, and biofouling evaluation <br />will be every two to four weeks. Well monitoring would be on a quarterly basis. <br />