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Mr. Eric Jenks 0 - 2 - 0 7 September 2000 <br />The report states that five monitoring wells encircle the JTF Stockton facility, and each well is <br />between 100 and 300 feet from suspected source areas. Although MW -2 and MW -3 are <br />upgradient and side gradient of the facility based on the first monitoring event, they contain <br />nitrate concentrations ranging from 79 to 102 mg/l. An additional well should be installed <br />upgradient of facility operational influences in order to determine background groundwater <br />quality. I concur with the report's recommendation that an upgradient well should be considered <br />after several quarters of monitoring are completed in order to verify the groundwater flow <br />direction. <br />Results of the Phase lI investigation of January 1999 (reported in the 1 July 1999 Site <br />Investigation Work Plan) show ammonium at 2,370 mg/kg in soil at 10 feet bgs at the old tank <br />farm, and an underlying grab groundwater sample showed ammonium at 1,120 mg/l (STO1). At <br />the applicator wash area, soil contains ammonium concentrations of approximately 1,000 mg/kg <br />from 0 to 10 feet bgs, but a grab groundwater sample only contained 1.5 mg/1 ammonium <br />(STO3). The subsequent grab groundwater investigation of November 1999 (reported in the 30 <br />January 2000 Site Investigation Work Report) found ammonium concentrations ranging from 95 <br />to 400 mg/l in the groundwater between STO1 and STO3. Even though the monitoring well <br />samples showed no detection of ammonium, it appears as though a significant source area for <br />ammonium may be present. Any remediation proposal for the site will need to address this <br />source area. <br />The November 1999 grab groundwater investigation found MTBE near the fuel island ranging <br />from 40 to 1,000 ug/1, and petroleum hydrocarbons as diesel ranging from not detected to 1,700 <br />ug/1. The monitoring well samples did not contain MTBE or petroleum hydrocarbons. Future <br />monitoring events will determine if these compounds are confined to the site. <br />Nitrate concentrations ranged from 69 mg/1 to 160 mg/1, significantly greater than the water <br />quality goal of 10 mg/l, and MW -5 contained 1,2,3-trichloropropane at 1.5 ug/1, higher than the <br />water quality goal of 0.005 ug/l. Additional monitoring wells and/or investigation may be <br />needed to identify the extent of constituent migration. Nitrate concentrations notwithstanding, I <br />concur with the report's conclusion that compounds detected in the grab groundwater <br />investigations are not laterally extensive. <br />The report proposes to obtain additional groundwater samples from the monitoring wells to <br />confirm the lateral extent of previously identified groundwater contaminants, and to determine <br />whether aquifer conditions are suitable for in-situ anaerobic biodegradation of volatile organic <br />compounds and nitrate. GeoSyntec proposes to analyze grab groundwater samples for oxidizable <br />nitrogen, ammonium, volatile organic compounds, and fumigants, in addition to general <br />chemistry parameters evaluating redox conditions. The parameters listed include a range of <br />water quality indicators that will present a view of the oxidation state of groundwater. I approve <br />the proposed work. <br />Draft MRP <br />A regular groundwater monitoring program is required for the monitoring wells to formally track <br />groundwater elevations, groundwater gradient, and constituent movements. A draft MRP is <br />