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No.468 Fuel Oil No. 1 11190
<br /> Section 6. Health Hazard Data continued s g.
<br /> pulmonary edema and consolidation.Last lung changes are no�in fatal rhythm me character
<br /> tiver,kidney,bone acute,
<br /> spleenmchanges.
<br /> bronchopneumonia.Other systemic effects include heart(potentially Yte
<br /> The mean oral lethal dose is-4 to 6 oz,with death occurring within 2 to 24 hr.Hemorrhaging and pulmonary edema,progressing to renal in-
<br /> volvement nerd chemical pneumonitis,may result if vomiting occurs after ingestion,and oil is aspirated into the lungs. Death may result from as
<br /> little as 12 oz,while survival is noted up to 12 oz ingested.Ingestions syystemic effect is primarily central nervous system(CNS)depression
<br /> which may lead to coma and respiratory depression.Gastrointestinal(Gq lining irritation may cause burning of mouth,esophagus,and stomach,
<br /> as well as vomiting,intestinal cramping,and blood-tinged diarrhea.Fuel oil No. I is irritating to skin and mucous membranes.Percutaneous ab-
<br /> sorption may be significant Prolonged contact may cause significant skin damage(epidermal necrolysis,or scalded skin appearance).Kidney
<br /> damage apppears to occur at higher fr uency after prolonged skin exposure.Eye contact with liquid or vapor may cause irritation.
<br /> Medical Conditlos Aggravated by Long Term Exposure:None reported.
<br /> Target Organs:Central nervous system,skin,and mucous membranes.
<br /> Primary Entry Routes:Inhalation,Ingestion.
<br /> Acute Effects:S9stemic effects from ingestion include GI irritation.vomiting,diarrhu
<br /> ea,and,in severe cases,CNS depression,progressing to
<br /> coma and death.Inhalation of aerosol or mists may result in increased respiration,tachycardia(excessively rapid heart beat),and cyanosis(dark
<br /> purplish coloration of skin and mucous membranes caused by deficient blood oxygenation).
<br /> Chronic Effects:Repeated skin cootact causes dermatitis.
<br /> FIRST AID
<br /> Eyes:Gently lift the eyelids and flush immediately and continuously with amounts of water until transported to an emergency medical
<br /> h flooding
<br /> facility.Consult a physician immediately.
<br /> Skin:Quickly remove contaminated clothing.Rinse with nooding amounts of water for at least 15 min.If large areas of the body are exposed or
<br /> if irritation persists,get medical help immediately.Wash affected area with soap and water.
<br /> Inhalation:Remove exposed person to fresh air and support breathing as needed.
<br /> Ingestion: Never give anything by mouth to an unconscious or convulsing person.If ingested,do not induce vomiting due to aspiration hazed.
<br /> Contact a physician immediately.
<br /> After first aid,get ap ropriate in-plant,paramedlc,or community medical support
<br /> Note to Physicians:Gastric lavage is conraindicated due to aspiration hazard.Preferred antidotes are charcoal and milk.In cases of severe
<br /> aspirtion pneumonitis,consider monitoring arterial blood gases to ensure adequate ventilation.Observe the patient for 6 M.If vital signs hecoinc
<br /> abnoramal or symptoms develop,obtain a chest x-ray.
<br /> Section 7. Spill, Leak, and Disposal Procedures
<br /> SPOUI.eak:Notify safetypersoonel,evacuate area for large spills,remove all heat and ignition sources,and provide maximum explosion-proof
<br /> ventilation.Cleanup personnel should Protect against vapor inhalation and liquid contact.Clean up spills promptly to reduce fur or vapor hazards.
<br /> Use a noncombustible absorbent material to pickup small spills or residues.For large spills,dike far ahead to contain.Pickup liquid for reclama-
<br /> tion or disposal.Do Dot release to sewers or waterways due to health and fire and/or explosion hazard.Follow applicable OSHA regulations(29
<br /> CFR 1910.120).'
<br /> Disposal:Contact your supplier or a licensed contractor for detailed recommendations.Follow applicable Federal,state,and local regulations.
<br /> EPA Designations
<br /> Listed as a RCRA Hazardous Waste(40 CFR 261.21):Ignitable waste
<br /> CERCLA Hazardous Substance(40 CFR 302.4 :Not listed
<br /> SARA Extremely Hazardous Substance(40 CFR 355):Not listed
<br /> SARA Toxic Chemical(40 CFR 372.65):Not listed
<br /> OSHA Designations
<br /> Air Contaminant(29 CFR 1910.1000,Subpart Z):Not listed
<br /> Section 8. Special Protection Data
<br /> Goggles:Wear protective eyeglasses or chemical safety goggles,per OSHA eye and face-protection regulations(29 CFR 1910.133).
<br /> Respirator:Seekrofessional advice prior to respirator selection and use.Follow OSHA respirator regulations(29 CFR 1910.134)and,if Deces-
<br /> sary,use a NIOSH-approved respirator with mist filter and organic vapor cartridge.For emergency or nouroutine operations(cleaning spills,
<br /> reactor vessels,or storage tanks),wear an SCBA.Warning!Aw-purifying respirators do not protect workers in oxygen-deficient aima5pheres.
<br /> Other:Wear impervious gloves,boots,aprons,and gauntlets to prevent skin contact.Nitrile or polyvinyl alcohol gloves are recommended.
<br /> Ventilation:Provide general and local explosion-proof ventilation systems to maintain airborne concentrations that promote worker safety and
<br /> productivity.Local exhaust ventilation is preferred since it prevents contaminant dispersion into the work area by controlling it at its source.
<br /> Scm
<br /> afety Stations:Make available in the work area emergency eyewash stations,safetylquick-drench showers,and washing facilities.
<br /> Contaminated Equipment:Never wear contact lenses lin the work area: soft lenses may absorb,and all lenses concentrate,irritants.Remove this
<br /> material from your shoes and equipment Launder contaminated clothing before wearing.
<br /> Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,
<br /> smoking,using the toilet,or applying cosmetics.
<br /> Section 9. Special Precautions and Comments
<br /> Storage Requirements: Use and storage conditions should be suitable for an OSHA Class Il combustible liquid.Store in closed containers in a
<br /> well-ventilated area away from heat and ignition sources and strong oxidizing agents.Protect containers from physical damage.To prevent static
<br /> sparks,electrically a ound and bond all containers and equipment used in shipping,receiving,or transferring operations.Use nonsparking tools
<br /> and explosion-prop electrical equipment.No smoking in areof storage or use.
<br /> Eingineering Controls:Avoid prolonged skin contact and vapor or mist inhalation.Use only in a well-ventilated area and with personal protec-
<br /> tive gear.Institute a respiratory protection program that includes regular training,maintenance,inspection,and evaluation.Practice good personal
<br /> hygiene and housekeeping procedures.Do Dot wear oil contaminated clothing.Do not put oily rags in pockets.When working with this material,
<br /> wear gloves or use barrier cream.
<br /> Transportation Data(49 CFR 172.101)
<br /> DOT Shipping Name: Fuel oil
<br /> DOT Hazard Class: Combustible liquid
<br /> ID No.: NA 1993
<br /> DOT Label:None
<br /> DOT Packaging Exceptions: 173.118a
<br /> DOT Packaging Requirements:None
<br /> arSDS Collection References: 1,6,7,12,73,84,103,126,131,132,133,136,143
<br /> Prepared by:MJ Allison,BS;Industrial Hygiene Review:DJ Wilson.CIH;Medical Review:w Silverman,MD;rdlted by:JR Smart,MS
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