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Materia!Safety Data Sheets Collection. <br /> Genlurn Publishing Corporation <br /> 1145 Catalyn Str= Sheet467 <br /> GP Schenectady,NY 12303-1836 US T Gasoline, Lead-free <br /> Sectional: J�fnt 7p (518)37-7-S854 IJSsued' 10/81 Revision: A, 9/91 <br /> mdrication <br /> Automotive ssolln��,.IrceLexrlpuon:Amature of <br /> I )Utlk hydrocarbo,,,c <br /> cyc Oraposed mainly of <br /> cards. <br /> Athabasca tax sands, and coal.Motor 8 --=n X I IN-7 <br /> rutphd�,,,.0 Zrontatics-In 9�'L 91301ine is prod.Od from Petroleum,shale oil- 1 2 <br /> es are made chiefly by awkiS P�"which <br /> con,cri heavies P'MI"m S 2- <br /> to ' -0 <br /> fractions into more volatile fractions by thermal or earn]y6c d,,,,mposition_Widely used <br /> rocs <br /> of the <br /> spa' -.8 <br /> ,:t of m <br /> cr'Sine's of the spark-igniLcd'lecil`(�ring type AuLOMOL"ve Easoline has an a n as fuel in internal combustion K 4 <br /> Entent 70f�omatic hydrocarbons Octan umb,of pproxim&Lcly 90.A high •Skin <br /> m and a corusequent high toxicity are also associated with a high octarte ra-Ling.Some <br /> 9&50lInc.s cold in the US contain a minor proportion Of Letraahyl-kad,whkh is added in ccm,,,nau, borpoco <br /> tper gallon to prevent engine"knOdL"'Howevcr,methyl-tcn-WrA cthcr(MTBE)h�almost Ons not exceeding 3 m] H <br /> =mthyl.le.ad. st Completely rtpL&xd F <br /> Otber <br /> l'AsnODIC41re�x.tio=CAS NO.8006-61-9.bcmzrigasoline,gacicac,motor rpfiits,nanral gasoline PR <br /> Contacyour supplier M dstibutcrConsult aLcV Chvnical Wept Bwy�'Guide'M foPr&oruppliezT <br /> list. t <br /> Cautions:Irjaja6.Of automotive gasoline vap,,,can cause intense hznrlg in throar <br /> and 9� L= <br /> dcPmsiOr4 C-ad poss�tble fatal PuIrrxmXrY edema.Gasc,line is a dangerous fire a explosion hags, <br /> s'ccntral�oa 1 (CNS) <br /> Section 2. Ingredients and Occupational--— osureLimits "'On hazard whM exPos-cd to hear and naM <br /> Expo�sum—Lfn,�j ————————— <br /> Automotive gasoline,lead-¢c<• <br /> 1990 OSHA PEI-s 1990-91 ACGIR TLVs 1985-96 Toxicity Data* <br /> 8-hr TWA.300 ppm,goo M&IM, 7WA--300 pprrL.890 01&0 <br /> 15-min STEL-500 ppm 1500 m&/m3an.inluslalion.TC,:900 ppmjj hr, <br /> joxtoxiceffwu L_,clu&c res <br /> STEL 500 ppm 1480 tag/msMorg"and tpwW scuus(conjunctiva ffivatianj bChAVIoraj <br /> L990 NIOSH REL <br /> (hADLICirIlliOns.distorted Perceptions),hmgx,thorny or <br /> �Prraron(cough) <br /> None,establishedHurnam eye, 140 ppnv8 hr. toxic tffacta include mild jrfi�' <br /> Rat.mh-I-L�LC,:300 hr, <br /> min <br /> A typical modem gasoline con1poitim is paraffins, <br /> sulfur,phocphcuj,andMMF- d 6T.ok&u.TIle mcan bctu=,cmtmt is approximately I Other ,Evu ad <br /> t See N'10SH.RTECS(IM300000),for&ddidmil taxi L data <br /> Section 3. Physical Data <br /> Bolling. rowu Ijutially 102 r(39 -L:);after lvf.Ms <br /> DSITYI.Npecinc GravIty:0.72 to 0.7�at 60 T(15.6 -C) <br /> T(110-C); ft,90%d;,Ined, Water SolubILIty:L=luble <br /> (60*C): after 50%��L�ed,230 i�1�5 T <br /> 338 T(170 'Q;final boning point 399 T(204'C) <br /> Vapor Density(air= 1):3.0 to 4.0 <br /> App"mwe and Odor.A clear may be colored with dye),mobile liquid with&characteristic odor rcmgnizable at about 10 pp, <br /> in a <br /> Section 4. tire and Explosion Data <br /> Flash rOw E: -45 -k-(43 'Q I Antolpi on <br /> exunguLZlng Media: Use 6 Temper-ature:536 to 853E (280 to 456 *Q LEL: 1-3%vIv LT�L-6.0% <br /> xide,or alcohol foam as <br /> but use waler'Prly to knock do�m vapont and to cool fere-exposed drums and tanks to prevent Pressure rupture, Do not use a solid su�,,t <br /> ex <br /> water since it may spread the fuel- C <br /> Unusual Fire or Explosion Hazards: Automobile gasoline is an OSHA Class IB flammable liquid and a dangerous fire and explosion hazzrd <br /> when exposed to heat and flames-Vapors can flow to&x1i ignition source and flash back-Automobile gasoline 0 <br /> agents, lin 1s react violently with ag <br /> Specl2l Fire-fighting Procedures:Isolate hazard area and deny entry-Since fir <br /> APParAtUs(SCBA)with a full faccpi�Op,,,&Lcd , e may Produce toxic fumes,w�a self-contained brta-,hing <br /> cxtinguishc�use nonsparIzit-q In or positivc-p,mode, and full protective clothing.When the fuer <br /> Section ; tools for clean Be Be Aware of runoff from fire C0noO1 methods.Do not Te1c,,.,to sewers or ww�ays. <br /> ect n 5- — ty Data <br /> Automotive gasoline is stable at room tcmpmOne in closed COnLain=und�no= <br /> Hazardous Polymerization cannot occur. 81 storage and handag <br /> Chem"I IncOmp2tiblildes: Automotive gasoline can react With oxidizing materials such as peroxides, r1illic acid, and Pcrchkm . <br /> Conditions to Avoid: Avoid heat and ignition sources. <br /> Hazardous Products of Decomposition:Thermal oxidative decomposition of automotive gasoline can produce 0 of car �d <br /> a�rbons. prod oxides ban pw� <br /> Oxidized hydroc <br />