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v <br /> r.. <br /> Shell MATERIAL SAFETY DATA SHEET <br /> MSDS Number: 53230E - 14 24 Hour Emergency Assistance: <br /> CHEMTEL (877) 276-7283 General Assistance Number: (877) 276- <br /> 7285 <br /> SECTION 1 PRODUCT IDENTIFICATION <br /> MATERIAL IDENTITY: Shell AR 4000 Paving Asphalt Cement <br /> PRODUCT CODES: 50246 <br /> COMPANY ADDRESS: Equilon Enterprises LLC, P. O. Box 4453, Houston, TX. 77210-4453 <br /> SECTION 2 PRODUCT/INGREDIENTS <br /> INGREDIENTS CAS# CONCENTRATION <br /> Asphalt Mixture 100 %volume <br /> Vacuum Tower Bottoms 64741-56-6 40 - 96 %volume <br /> Heavy Naphthenic Petroleum Distillates 64741-53-3 4 -60 %volume <br /> Hydrogen Sulfide 7783-06-4 < 01 %weight <br /> NOTE: H2S is a naturally occuring constituent in the petroleum stream and is not added <br /> separately to the product. <br /> SECTION 3 HAZARDS IDENTIFICATION <br /> EMERGENCY OVERVIEW Appearance & Odor: Black viscous semi-solid. Asphalt or rotten egg <br /> odor. Health Hazards: Hydrogen sulfide (1-12S), an extremely flammable and toxic gas, may be <br /> present. Contact with hot material will cause thermal burns. NFPA Rating (Health, Fire, <br /> Reactivity): 1, 1, 0 Hazard Rating:Least- 0 Slight- 1 Moderate -2 High - 3 Extreme-4 <br /> Inhalation: <br /> In applications where vapors (caused by high temperature) or mists (caused by mixing or <br /> spraying) are created, breathing may cause a mild burning sensation in the nose, throat and <br /> lungs. Hydrogen Sulfide (H2S) and other hazardous vapors may evolve and collect in the <br /> headspace of storage tanks or other enclosed vessels. Hydrogen Sulfide is an extremely <br /> Flammable, toxic gas. Inhalation of vapors, mist or fumes (generated at high temperatures) may <br /> cause irritation to the nose, throat and respiratory tract. <br /> Eye Irritation: <br /> Contact with hot material can cause thermal burns which may result in permanent damage or <br /> blindness. Based on essentially similar product testing, cool product is presumed to be minimally <br /> irritating to the eyes. <br /> Skin Contact: <br /> Contact with hot material can cause thermal burns which may result in permanent damage. Other <br /> adverse effects not expected from brief skin contact. Based on essentially similar product testing, <br /> cool product is presumed to be minimally irritating to the skin. <br />