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i /¢ l• <br /> R <br /> values increase, it can mean incorrect proportions of the chemical <br /> ingredients has taken place. <br /> An increase in normal compression set values does require im- <br /> mediate action to determine the cause. <br /> Another accelerated test for urethane foam is humidity aging. <br /> Resistance to humidity or more precisely, the change in the physical <br /> properties of the foam after this accelerated aging is the last of the <br /> physical properties we will examine. Various conditions for this <br /> accelerated test have been established, the most common and most <br /> severe is a 5 hour period at 250 degrees F. or approximately 15 lbs. <br /> saturated steam pressure. <br /> It is possible for any physical test we have discussed to be repeated <br /> after the accelerated aging and the change in measurement evaluated. <br /> Low density foams with their larger percentage of urea cross links <br /> and large exotherm do give excellent results in the two areas most <br /> closely examined, namely compression set and 25% ILD. Both values <br /> will remain fairly constant. Their resistance to this test should not be <br /> interpreted as giving "trouble-free" use in service. <br /> Conditions of high humidity and high temperatures will attack the <br /> urethane linkage to a somewhat greater degree. High density foams <br /> with their greater concentration of these urethane linkages may have <br /> a greater change in properties after humidity aging. This greater <br /> change should not give concern to the user. <br /> What must be examined are the severity of the conditions of test <br /> and their relationship to service life. High density polyether urethane <br /> foams have been in service for approximately ten years and no <br /> indication of failure because of humid conditions is evident. <br /> As with the other properties there is a normal value for each formu- <br /> lation and the continuous monitoring will indicate a production varia- <br /> tion when it occurs. <br /> We have examined the chemistry and properties of the present <br /> foams available. What new products does the urethane industry have <br /> to offer? The tire and rubber industry have for years used carbon <br /> blacks to reinforce their products. <br /> The urethane foam industry is turning to this same concept of <br /> reinforcement to increase foam firmness. <br /> Union Carbide has recently introduced a new polyol. Incorporated <br /> into the polyol chain are different chemical groups. The first polyol <br /> they have offered contains vinyl groups. These groups physically <br /> reinforce the urethane chains to produce firmness. <br /> In addition to these organic materials, finely divided inorganic <br /> materials will also contribute a reinforcing action. Most of the rein- <br /> forced or heavy density foams on the market today use this technique. <br /> 11 <br />