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ROADWAY <br /> • <br /> Chemical Release Procedures <br /> Supervisor Assessment Chart <br /> All supervisors shall review this document to determine the hazards of cleaning-up a hazardous material/chemical incidental spill. Note: <br /> Evaluate all chemical hazards,both primary and secondary. An incidental spill is one where there is no danger of fire,explosion,or <br /> chemical exposure to the employee cleaning-up the spill. Call the Chemical I-lelpline at 800-395-5446.Option 1,if the atmosphere in file <br /> spill arca is unknown or if the released product has inhalation,fire or explosive hazards. If at any time you are in doubt of the correct <br /> procedure to follow,call the Chemical Helpline. <br /> HuMat Class Hazards Procedure Personal Protective Equipment <br /> CLASS 1- Division 1.4;1.5;1.6 Caution: Keep awayjrom Goggles for flash protection of <br /> EXPLOSIVES- Minor explosive hazard with no ignition sources(heat sparks, eyes <br /> mass explosion and no projection flames).Avoid creatingfriction <br /> of fragments of appreciable size by withdrawing jorkhft blades <br /> or range. from penetrated container or <br /> Sensitive to shock and heat. draggingjreight on dock <br /> CLASS 2- Div.2.1 is flammable Div. 2.1-If valve is leaking <br /> COMPRESSED GASES evacuate area and immediately <br /> contact Chemical Helpline <br /> Keep ignition sources away <br /> ' including forklifts. <br /> Div.2.2 is non-flammable Div.2.2-Let pressurized <br /> material escape. <br /> <NIAIA710tt�. Div.2.3 is poisonous Div. 2.3-If valve is leaking <br /> \ 'ea2otu <br /> �/.' <br /> evacuate area and immediately <br /> All cylinders are under pressure. contact Chemical Helpline <br /> CLASS 3- 1. Material is flammable,will If there is a potential release,or Goggles,gloves,apron and <br /> FLAMMABLE readily ignite from common a detectable odor, eye or nose boots. On all visible liquid spills, <br /> LIQUIDS sources(heat,spark or irritation contact Chemical sprinkle absorbent onto the <br /> flame). Helpline before initiating material until the mixture is <br /> Packing Groups 1,II& 2. Contact may cause bums to cleanup. absorbed. If there is noticeable <br /> III the eyes or skin Have a fire extinguisher ready skin irritation due to fumes or <br /> 3. Fire may produce irritating for immediate use by a second vapors,do not attempt to <br /> or poisonous gases person wearing the same continue clean up,call the <br /> 4. May be poisonous if inhaled protective equipment in case of a Chemical Helpline for assistance. <br /> or swallowed fire. Containerize the absorbed <br /> Note:The material may be toxic material into a recovery drum <br /> as well&flammable.Review Caution: Keep all sources of with chemical liner using a clean <br /> shipping papers to determine if ignition away from substance non-sparking shovel or dustpan. <br /> the material is toxic(poison). includingjorklifts. Avoid If the package is wet,but there is <br /> creating friction or sparks no noticeable liquid place the <br /> package into a recovery drum <br /> with chemical liner. <br /> Issued by Safety Services <br /> Revised: 07-01-04 HM-135R (laminated version) <br />