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• Chemical Release Procedures • <br /> Supervisor Assessment Chart <br /> H=Mat Class Hazards Procedure Personal Protective Equipment <br /> CLASS 4- 1. 4.1 is flammable,will Keep all sources of ignition Goggles,gloves,apron and boots. <br /> 4.1 FLAMMABLE readily ignite from away from the substance Avoid any activity that will cause the <br /> SOLIDS common sources of heat, including forklifts. Avoid material to become airborne. Use a <br /> 4.2 SPONTANEOUSLY sparks or flames&is creating friction or sparks. clean plastic non-sparking shovel or <br /> COMBUSTIBLE thermally unstable. 4.2 dustpan to move the material into a <br /> 4.3 DANGEROUS includes pyrophoric Caution: Do not add recovery drum with chemical drum <br /> WHEN WET liquids and solids self- neutralizer to Division 41 liner. <br /> heating materials,which material <br /> can ignite within 5 Do not add water to Division <br /> minutes after exposure to 4.3 material <br /> air without external <br /> ignition sources. 4.3 <br /> reacts with water and <br /> produces flammable or <br /> i. •i toxic gas. <br /> 2. Contact may cause bums <br /> to the eyes or skin <br /> 3. Fire may produce <br /> irritating or poisonous <br /> gases <br /> 4. May be poisonous if <br /> inhaled or swallowed <br /> Caution: The material may <br /> be toxic as well&flammabLe <br /> CLASS 5.1 OXIDIZERS 1. Contact may cause bums If there is a potential release, Goggles,gloves,apron and boots. <br /> to the eyes or skin. or a detectable odor,eye or On liquid spills,sprinkle absorbent <br /> 2. Material is not time irritation contact onto the material until the mixture <br /> flammable,but causes Chemical Helpline before appears dry. <br /> +ADU <br /> other materials to bum initiating cleanup. Containerize the absorbed material <br /> and generates oxygen. Have a fire extinguisher into a recovery drum with chemical <br /> ready for immediate use by a drum liner using a clean shovel or <br /> Caution: The material may second person wearing the dustpan. <br /> be toxic as well as an same protective equipment. If the box is wet,but there is no <br /> oxidizer Prevent liquid from coming noticeable liquid place the box into a <br /> into contact with other boxes recovery drum with chemical drum <br /> or flammable materials. liner. <br /> Safely move the damaged Call the shipper to obtain specific <br /> material and packing box to neutralization instructions. <br /> an area that will be safe if it <br /> were to catch on fire. Caution:Never put an oxidizer into <br /> a steel recovery drum without a <br /> chemical liner! <br /> Issued by Safety Services <br /> Revised: 07-01-04 IIM-I35R (laminated version) <br />