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STANDARD OPERATING PROCEDURE <br /> GROUNDWATER SAMPLING <br /> Gettler-Ryan Inc. field personnel adhere to the following procedures for the collection and handling of <br /> groundwater samples prior to analysis by the analytical laboratory. Prior to sample collection,the type <br /> of analysis to be performed is determined. Loss prevention of volatile compounds is controlled and <br /> sample preservation for subsequent analysis is maintained. <br /> Prior to sampling,the presence or absence of free-phase hydrocarbons is determined using an interface <br /> probe. Product duckness,if present,is measured to the nearest 0.01 foot and is noted in the field notes. <br /> In addition,static water level measurements are collected with the interface probe and are also recorded <br /> - in the field notes. <br /> After water levels-arected <br /> ollec =and-prior-to-sampling,-each=well=is_purged a minimum_o€_three well <br /> casing volumes of water using pre-cleaned Pumps (stack, suction, Grundfos), or polyvinyl chloride <br /> bailers. Temperature,pH and electrical conductivity-are meaisured a minimum of three tines during the <br /> purging. Purging continues until these parameters stabilize. <br /> Groundwater samples are collected using Chevron-designated disposable bailers. The water samples are <br /> transferred from the bailer into appropriate containers. Pre-preserved containers, supplied by analytical <br /> laboratories,are used when possible. When pre-preserved containers are not available,the laboratory is <br /> instructed to preserve the sample as appropriate. Duplicate samples are collected for the laboratory to <br /> use. maintaining quality assurancelquality control standards. The samples are labeled to include the <br /> job number,sample identification,collection date and time,analysis,preservation(if airy),and the sample <br /> collector's initials. The water samples are placed in a cooler, maintained at 4oC for transport to the <br /> laboratory. Once collected in the field,all samples are maintained under chain of custody until delivered <br /> to the laboratory. <br /> The chain of custody document includes the job number,type of Preservation,if any,analysis requested, <br /> sample identification,date and time collected,and the sample collector's name. The chain of custody is <br /> signed and dated (including time of transfer) by each person who receives or surrenders the samples, <br /> beginning with the field personnel and ending with the laboratory personneL <br /> A laboratory supplied trip blank accompanies each sampling set. For sampling sets greater than 20 <br /> samples,5%trip blanks are included. The trip blank is analyzed for some or all of the same conapotmds <br /> as the groundwater samples. <br /> As requested by Chevron Products Company, the purge water and decontamination water generated <br /> during sampling activities is transported by 1WM to McKittnck Waste Management located in <br /> McKittrick,California <br /> s, .sroo <br />