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Chevron Products CompanyPage 2 <br /> Chevron Service Station#9-0557,Qouth Center Street,Stockton,California November 28,2001 <br /> The ozone reaction is most effective in a gaseous phase, where ozone concentrations are <br /> higher at the point of saturation than in liquid. As a result, the method of delivery to the <br /> subsurface significantly impacts treatment effectiveness. OS is a process that couples ozone <br /> generation with air sparging. Bubbles injected into the subsurface by sparging volatilize <br /> dissolved constituents into the gas phase where they react with ozone. The reaction between <br /> organic substrates (R) and ozone (03) forms primary ozonides. The ozonide is extremely <br /> unstable, and decomposes rapidly, thus mineralizing the substrate. For treating benzene, the <br /> reaction is: <br /> 03 + C6H6 —), HC-03-05H5 (ozonide of benzene) <br /> 403 + HC-03-C5H5 —> 6CO2 + 3H2O <br /> A variety of other competing reactions involving naturally occurring organic and inorganic <br /> constituents also consume the ozone. Therefore, reagent-dosing requirements are site- <br /> specific and should be based on pilot testing. <br /> The treatment is commonly performed by injecting target strata at source areas and/or hotspot <br /> locations with the carrier gas/ozone mixture. Important factors for successful ozone sparging <br /> are the permeability and heterogeneity of the subsurface. These factors, in turn, affect the <br /> treatment zone size and the treatment efficiency. Therefore, injection rate and point spacing <br /> is site-specific and should be based on pilot testing. <br /> Pilot Test Facility Installation <br /> The scope of the pilot testing will include the drilling and installation of four(4) dual <br /> completion OS sparge points (Figure 2) and the performance of a three-month,minimum, OS <br /> pilot test. Details of each activity are summarized in the following bullets. <br /> • Pre-mobilization Planning. A site-specific Health and Safety Plan(HASP) will be <br /> prepared for all SECOR employees and for reference by SECOR subcontractors. The <br /> HASP will be prepared in accordance with procedures outlined in Appendix A. An <br /> effort to locate utilities in the proposed work areas will be performed by either <br /> Underground Service Alert (USA) or through a private utility locating company. <br /> ■ Permitting. The applicable permits for the OS wells will be obtained from SJCEHD <br /> prior to drilling. <br /> • OS Wells. Four(4) soil borings will be advanced at the locations shown on Figure 2 <br /> using 8-inch diameter hollow-stem augers to approximately 45 feet bgs. SECOR will <br /> not collect soil or groundwater samples from the boreholes for chemical analysis. <br /> Upon completion of drilling, dual completion ozone sparge points will be installed in <br /> each of the boreholes (for a total of eight [8] sparge points). The sparge points will <br /> be completed to approximate depths of 30 and 45 feet bgs, respectively, in each <br /> borehole. Field procedures for the installation of the ozone sparge points are <br /> I:\Chevron\90557\REPORTS\Feasibility Study\03—Addendum.doc. <br />