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James L. Tjosvold, P.E. <br /> February 23, 1995 <br /> Page 3 <br /> • Limit VOC analysis to benzene, toluene, ethyl benzene, and xylene (BTEX) <br /> because these are the only VOC compounds that have been detected in any of the <br /> Zone A wells (other than a one time detection of tert-butyl-methyl ether in MW-2). <br /> • Add a one time analysis (in March, 1995) for barium and antimony to support the <br /> feasibility study. The concentration of these compounds exceeded the MCLS in a <br /> previous sampling event. Additional sampling is needed to determine if these can <br /> be attributed to upgradient concentrations. <br /> • Add a one time analysis of cyanide for MW-9 because this constituent exceeded <br /> the MCL in a previous sampling event. <br /> In summary, on-site wells MWA, MWA and MW-8 would be deleted from the sampling <br /> program. PG&E would monitor new wells MWAR and MW-18 quarterly, and existing <br /> perimeter wells MW-2, MW-3, MW-7, MW-9, MW-10, MW-11 and MW-12 annually. <br /> Water levels would be measured quarterly in all wells. The proposed revised program is <br /> presented in Table 1. <br /> Zone B: <br /> The Workplan specifies that samples from Zone B wells will be analyzed quarterly for <br /> PNAs and VOCs. The rationale was to evaluate concentrations of chemicals previously <br /> detected (PNAs) and confirm previous results (no VOCs present). <br /> PG&E recommends the following revisions to the monitoring program for Zone B wells: <br /> • Delete MW-5 from the sampling program. MW-5 is located in the center of the <br /> site and is surrounded by five Zone B wells. Concentrations in the Zone B wells <br /> are similar and this well is not necessary to characterize the nature and extent of <br /> constituents in the groundwater. <br /> • Reduce the frequency of sampling from quarterly to annually in the Zone B wells <br /> installed prior to the Phase III investigation (MW-1D and MW-6). These wells <br /> have been sampled eight and seven times respectively and PNA and VOC <br /> concentrations have been fairly consistent in these wells. Annual monitoring will <br /> be sufficient to monitor temporal changes in groundwater quality. <br /> • Limit VOC analysis to BTEX and add a one time analysis for antimony and barium <br /> for the reason stated for the Zone A wells. <br />